Simple method for the handling of crystals at low temperature: Application to the x-ray structure determination of Bu2tP(=NSiMe 3)NHSiMe3 and [Bu2tP(NSiMe 3)2]Li·thf2

Alison J. Edwards; Eric Wenger

doi:10.1071/CH02016

Simple method for the handling of crystals at low temperature: Application to the x-ray structure determination of Bu₂^tP(=NSiMe ₃)NHSiMe₃ and [Bu₂^tP(NSiMe ₃)₂]Li·thf₂

Alison J. Edwards, Eric Wenger^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Crystals of the very soluble iminophosphonamide species Bu₂ ^tP(=NSiMe₃)NHSiMe₃ (1) and [Bu^t ²P(NSiMe₃)₂]Li·(thf)₂ (2) have been obtained and were mounted at dry-ice temperature using a propan-2-ol matrix for X-ray data collection at 100 K. This very simple method for handling the crystals at low temperature is described together with the resulting molecular structures of (1) and (2).

Original language	English
Pages (from-to)	249-252
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	55
Issue number	4
DOIs	https://doi.org/10.1071/CH02016
Publication status	Published - 2002

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abstract = "Crystals of the very soluble iminophosphonamide species Bu2 tP(=NSiMe3)NHSiMe3 (1) and [But 2P(NSiMe3)2]Li·(thf)2 (2) have been obtained and were mounted at dry-ice temperature using a propan-2-ol matrix for X-ray data collection at 100 K. This very simple method for handling the crystals at low temperature is described together with the resulting molecular structures of (1) and (2).",

author = "Edwards, {Alison J.} and Eric Wenger",

year = "2002",

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pages = "249--252",

journal = "Australian Journal of Chemistry",

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AU - Edwards, Alison J.

AU - Wenger, Eric

PY - 2002

Y1 - 2002

N2 - Crystals of the very soluble iminophosphonamide species Bu2 tP(=NSiMe3)NHSiMe3 (1) and [But 2P(NSiMe3)2]Li·(thf)2 (2) have been obtained and were mounted at dry-ice temperature using a propan-2-ol matrix for X-ray data collection at 100 K. This very simple method for handling the crystals at low temperature is described together with the resulting molecular structures of (1) and (2).

AB - Crystals of the very soluble iminophosphonamide species Bu2 tP(=NSiMe3)NHSiMe3 (1) and [But 2P(NSiMe3)2]Li·(thf)2 (2) have been obtained and were mounted at dry-ice temperature using a propan-2-ol matrix for X-ray data collection at 100 K. This very simple method for handling the crystals at low temperature is described together with the resulting molecular structures of (1) and (2).

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U2 - 10.1071/CH02016

DO - 10.1071/CH02016

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SN - 0004-9425

VL - 55

SP - 249

EP - 252

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 4

ER -

Simple method for the handling of crystals at low temperature: Application to the x-ray structure determination of Bu₂^tP(=NSiMe ₃)NHSiMe₃ and [Bu₂^tP(NSiMe ₃)₂]Li·thf₂

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