Soluble Tetraaminotriptycene Precursors

Nicholas G. White; Mark J. MacLachlan

doi:10.1021/acs.joc.5b01221

Soluble Tetraaminotriptycene Precursors

Nicholas G. White, Mark J. MacLachlan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

An efficient route to soluble triptycene tetraamines, shape-persistent molecules containing two ortho-phenylenediamine motifs, is reported. These tetraamines are stable, prepared in good yields, easily purified by column chromatography, and can be readily condensed to give a range of imidazole and pyrazine derivatives.

Original language	English
Pages (from-to)	8390-8397
Number of pages	8
Journal	Journal of Organic Chemistry
Volume	80
Issue number	16
DOIs	https://doi.org/10.1021/acs.joc.5b01221
Publication status	Published - 21 Aug 2015
Externally published	Yes

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10.1021/acs.joc.5b01221

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title = "Soluble Tetraaminotriptycene Precursors",

abstract = "An efficient route to soluble triptycene tetraamines, shape-persistent molecules containing two ortho-phenylenediamine motifs, is reported. These tetraamines are stable, prepared in good yields, easily purified by column chromatography, and can be readily condensed to give a range of imidazole and pyrazine derivatives.",

author = "White, \{Nicholas G.\} and MacLachlan, \{Mark J.\}",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

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doi = "10.1021/acs.joc.5b01221",

language = "English",

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AU - White, Nicholas G.

AU - MacLachlan, Mark J.

PY - 2015/8/21

Y1 - 2015/8/21

N2 - An efficient route to soluble triptycene tetraamines, shape-persistent molecules containing two ortho-phenylenediamine motifs, is reported. These tetraamines are stable, prepared in good yields, easily purified by column chromatography, and can be readily condensed to give a range of imidazole and pyrazine derivatives.

AB - An efficient route to soluble triptycene tetraamines, shape-persistent molecules containing two ortho-phenylenediamine motifs, is reported. These tetraamines are stable, prepared in good yields, easily purified by column chromatography, and can be readily condensed to give a range of imidazole and pyrazine derivatives.

UR - https://www.scopus.com/pages/publications/84940063815

U2 - 10.1021/acs.joc.5b01221

DO - 10.1021/acs.joc.5b01221

M3 - Article

SN - 0022-3263

VL - 80

SP - 8390

EP - 8397

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 16

ER -

Soluble Tetraaminotriptycene Precursors

Abstract

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