Some More Transition Metal Acetylides

Michael I. Bruce; Mark G. Humphrey; Janis G. Matisons; Salil K. Roy; A. Geoffrey Swincer

doi:10.1071/CH9841955

Some More Transition Metal Acetylides

Michael I. Bruce^*, Mark G. Humphrey, Janis G. Matisons, Salil K. Roy, A. Geoffrey Swincer

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

115 Citations (Scopus)

Abstract

Routes developed for the syntheses of s-acetylide complexes of tungsten, iron, nickel, copper and silver include reactions of metal halide complexes with alk-1-ynes in organic amines, with copper(I) halides as catalysts, or in methanol in the presence of sodium methoxide. Yields range from good to excellent, and the reactions are generally simpler to carry out than previous methods.

Original language	English
Pages (from-to)	1955-1961
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	37
Issue number	9
DOIs	https://doi.org/10.1071/CH9841955
Publication status	Published - 1984
Externally published	Yes

Access to Document

10.1071/CH9841955

Cite this

@article{eb024cf6a8fc4d88bacb6862e959bfea,

title = "Some More Transition Metal Acetylides",

abstract = "Routes developed for the syntheses of s-acetylide complexes of tungsten, iron, nickel, copper and silver include reactions of metal halide complexes with alk-1-ynes in organic amines, with copper(I) halides as catalysts, or in methanol in the presence of sodium methoxide. Yields range from good to excellent, and the reactions are generally simpler to carry out than previous methods.",

author = "Bruce, {Michael I.} and Humphrey, {Mark G.} and Matisons, {Janis G.} and Roy, {Salil K.} and {Geoffrey Swincer}, A.",

year = "1984",

doi = "10.1071/CH9841955",

language = "English",

volume = "37",

pages = "1955--1961",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO",

number = "9",

}

TY - JOUR

T1 - Some More Transition Metal Acetylides

AU - Bruce, Michael I.

AU - Humphrey, Mark G.

AU - Matisons, Janis G.

AU - Roy, Salil K.

AU - Geoffrey Swincer, A.

PY - 1984

Y1 - 1984

N2 - Routes developed for the syntheses of s-acetylide complexes of tungsten, iron, nickel, copper and silver include reactions of metal halide complexes with alk-1-ynes in organic amines, with copper(I) halides as catalysts, or in methanol in the presence of sodium methoxide. Yields range from good to excellent, and the reactions are generally simpler to carry out than previous methods.

AB - Routes developed for the syntheses of s-acetylide complexes of tungsten, iron, nickel, copper and silver include reactions of metal halide complexes with alk-1-ynes in organic amines, with copper(I) halides as catalysts, or in methanol in the presence of sodium methoxide. Yields range from good to excellent, and the reactions are generally simpler to carry out than previous methods.

UR - http://www.scopus.com/inward/record.url?scp=0000630424&partnerID=8YFLogxK

U2 - 10.1071/CH9841955

DO - 10.1071/CH9841955

M3 - Article

AN - SCOPUS:0000630424

SN - 0004-9425

VL - 37

SP - 1955

EP - 1961

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 9

ER -

Some More Transition Metal Acetylides

Abstract

Access to Document

Other files and links

Fingerprint

Cite this