Spectroscopic and structural characterization of products arising from the base-promoted benzylation of 3-sulfolene

Muriel Bonnet; Martin G. Banwell; Anthony C. Willis; Vito Ferro

Spectroscopic and structural characterization of products arising from the base-promoted benzylation of 3-sulfolene

Muriel Bonnet, Martin G. Banwell^*, Anthony C. Willis, Vito Ferro

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Reaction of the title sulfone (1) with benzyl iodide at -78°C in the presence of LiHMDS and using THF/DMPU as solvent affords a chromatographically separable mixture of the compounds 2-5 in a combined yield of 42%. These products have been subjected to comprehensive spectroscopic characterization and the structures of products 2 and 5 established through single-crystal X-ray analyses.

Original language	English
Pages (from-to)	35-41
Number of pages	7
Journal	Arkivoc
Volume	2006
Issue number	10
Publication status	Published - 2006

Cite this

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title = "Spectroscopic and structural characterization of products arising from the base-promoted benzylation of 3-sulfolene",

abstract = "Reaction of the title sulfone (1) with benzyl iodide at -78°C in the presence of LiHMDS and using THF/DMPU as solvent affords a chromatographically separable mixture of the compounds 2-5 in a combined yield of 42%. These products have been subjected to comprehensive spectroscopic characterization and the structures of products 2 and 5 established through single-crystal X-ray analyses.",

keywords = "1,3-Butadienes, 3-Sulfolene, Benzylation, Fragmentation",

author = "Muriel Bonnet and Banwell, {Martin G.} and Willis, {Anthony C.} and Vito Ferro",

year = "2006",

language = "English",

volume = "2006",

pages = "35--41",

journal = "Arkivoc",

issn = "1551-7004",

publisher = "Arkat USA",

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T1 - Spectroscopic and structural characterization of products arising from the base-promoted benzylation of 3-sulfolene

AU - Bonnet, Muriel

AU - Banwell, Martin G.

AU - Willis, Anthony C.

AU - Ferro, Vito

PY - 2006

Y1 - 2006

N2 - Reaction of the title sulfone (1) with benzyl iodide at -78°C in the presence of LiHMDS and using THF/DMPU as solvent affords a chromatographically separable mixture of the compounds 2-5 in a combined yield of 42%. These products have been subjected to comprehensive spectroscopic characterization and the structures of products 2 and 5 established through single-crystal X-ray analyses.

AB - Reaction of the title sulfone (1) with benzyl iodide at -78°C in the presence of LiHMDS and using THF/DMPU as solvent affords a chromatographically separable mixture of the compounds 2-5 in a combined yield of 42%. These products have been subjected to comprehensive spectroscopic characterization and the structures of products 2 and 5 established through single-crystal X-ray analyses.

KW - 1,3-Butadienes

KW - 3-Sulfolene

KW - Benzylation

KW - Fragmentation

UR - http://www.scopus.com/inward/record.url?scp=33344469685&partnerID=8YFLogxK

M3 - Article

SN - 1551-7004

VL - 2006

SP - 35

EP - 41

JO - Arkivoc

JF - Arkivoc

IS - 10

ER -

Spectroscopic and structural characterization of products arising from the base-promoted benzylation of 3-sulfolene

Abstract

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