Stannylene or metallastanna(IV)ocane: A matter of formalism

Erica Brendler; Erik Wächtler; Thomas Heine; Lyuben Zhechkov; Thorsten Langer; Rainer Pöttgen; Anthony F. Hill; Jörg Wagler

doi:10.1002/anie.201007967

Stannylene or metallastanna(IV)ocane: A matter of formalism

Erica Brendler, Erik Wächtler, Thomas Heine, Lyuben Zhechkov, Thorsten Langer, Rainer Pöttgen, Anthony F. Hill, Jörg Wagler^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl₂ to a Pd^II complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd ^I-Sn^III) and palladastanna(IV)ocane (Pd⁰ Sn^IV) descriptions over stannylene coordination.

Original language	English
Pages (from-to)	4696-4700
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	20
DOIs	https://doi.org/10.1002/anie.201007967
Publication status	Published - 9 May 2011

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title = "Stannylene or metallastanna(IV)ocane: A matter of formalism",

abstract = "Pushmi-pullyu with palladium: Although created by {\"I}a donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal {\"I}a donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.",

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AU - Brendler, Erica

AU - Wächtler, Erik

AU - Heine, Thomas

AU - Zhechkov, Lyuben

AU - Langer, Thorsten

AU - Pöttgen, Rainer

AU - Hill, Anthony F.

AU - Wagler, Jörg

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N2 - Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.

AB - Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.

KW - coordination chemistry

KW - hypercoordination

KW - palladium

KW - tin

KW - transition-metal basicity

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IS - 20

ER -

Stannylene or metallastanna(IV)ocane: A matter of formalism

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