Stannylene or metallastanna(IV)ocane: A matter of formalism

Erica Brendler, Erik Wächtler, Thomas Heine, Lyuben Zhechkov, Thorsten Langer, Rainer Pöttgen, Anthony F. Hill, Jörg Wagler*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    45 Citations (Scopus)

    Abstract

    Pushmi-pullyu with palladium: Although created by Ïa donation from SnCl2 to a PdII complex, the Sn-Pd bonds in the compounds depicted exhibit formal Ïa donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I-SnIII) and palladastanna(IV)ocane (Pd0 SnIV) descriptions over stannylene coordination.

    Original languageEnglish
    Pages (from-to)4696-4700
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume50
    Issue number20
    DOIs
    Publication statusPublished - 9 May 2011

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