Sterically induced transmutations in cobalt amine chemistry

Rodney J. Geue; C. Jin Qin; Stephen F. Ralph; Alan M. Sargeson; Brian W. Skelton; Allan H. White; Anthony C. Willis

doi:10.1039/a907237c

Sterically induced transmutations in cobalt amine chemistry

Rodney J. Geue^*
, C. Jin Qin
, Stephen F. Ralph
, Alan M. Sargeson
, Brian W. Skelton
, Allan H. White
, Anthony C. Willis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN₆ chemistry, leading to Co(III/II)N₆ redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.

Original language	English
Pages (from-to)	2351-2352
Number of pages	2
Journal	Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/a907237c
Publication status	Published - 7 Dec 1999

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title = "Sterically induced transmutations in cobalt amine chemistry",

abstract = "Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.",

author = "Geue, \{Rodney J.\} and Qin, \{C. Jin\} and Ralph, \{Stephen F.\} and Sargeson, \{Alan M.\} and Skelton, \{Brian W.\} and White, \{Allan H.\} and Willis, \{Anthony C.\}",

year = "1999",

month = dec,

day = "7",

doi = "10.1039/a907237c",

language = "English",

pages = "2351--2352",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Sterically induced transmutations in cobalt amine chemistry

AU - Geue, Rodney J.

AU - Qin, C. Jin

AU - Ralph, Stephen F.

AU - Sargeson, Alan M.

AU - Skelton, Brian W.

AU - White, Allan H.

AU - Willis, Anthony C.

PY - 1999/12/7

Y1 - 1999/12/7

N2 - Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.

AB - Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.

UR - https://www.scopus.com/pages/publications/0033534104

U2 - 10.1039/a907237c

DO - 10.1039/a907237c

M3 - Article

SN - 1359-7345

SP - 2351

EP - 2352

JO - Chemical Communications

JF - Chemical Communications

IS - 23

ER -

Sterically induced transmutations in cobalt amine chemistry

Abstract

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