197Au Mössbauer spectroscopic studies of cyclometalated golddimers containing 2-C6F4PPh2 ligands

Martin A. Bennett, Nedaossadat Mirzadeh, Steven H. Privér, Masashi Takahashi, Suresh K. Bhargava

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    4 Citations (Scopus)

    Abstract

    197Au Móssbauer spectra have been measured on a series of homovalent and heterovalent dinuclear gold complexes containing the 2-C 6F4PPh2 ligand. The correlation plot indicates that the electron densities of the 6s and 6p orbitalsof the gold atoms in these complexes are less than those of their protio and 6-methyl analogs, reflecting the electronwithdrawing property of the fluorine substituents.

    Original languageEnglish
    Pages (from-to)1506-1509
    Number of pages4
    JournalBulletin of the Chemical Society of Japan
    Volume82
    Issue number12
    DOIs
    Publication statusPublished - 2009

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