197Au Mössbauer spectroscopic studies of cyclometalated golddimers containing 2-C6F4PPh2 ligands

Martin A. Bennett; Nedaossadat Mirzadeh; Steven H. Privér; Masashi Takahashi; Suresh K. Bhargava

doi:10.1246/bcsj.82.1506

¹⁹⁷Au Mössbauer spectroscopic studies of cyclometalated golddimers containing 2-C₆F₄PPh₂ ligands

Martin A. Bennett, Nedaossadat Mirzadeh, Steven H. Privér, Masashi Takahashi, Suresh K. Bhargava

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

¹⁹⁷Au Móssbauer spectra have been measured on a series of homovalent and heterovalent dinuclear gold complexes containing the 2-C ₆F₄PPh₂ ligand. The correlation plot indicates that the electron densities of the 6s and 6p orbitalsof the gold atoms in these complexes are less than those of their protio and 6-methyl analogs, reflecting the electronwithdrawing property of the fluorine substituents.

Original language	English
Pages (from-to)	1506-1509
Number of pages	4
Journal	Bulletin of the Chemical Society of Japan
Volume	82
Issue number	12
DOIs	https://doi.org/10.1246/bcsj.82.1506
Publication status	Published - 2009

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abstract = "197Au M{\'o}ssbauer spectra have been measured on a series of homovalent and heterovalent dinuclear gold complexes containing the 2-C 6F4PPh2 ligand. The correlation plot indicates that the electron densities of the 6s and 6p orbitalsof the gold atoms in these complexes are less than those of their protio and 6-methyl analogs, reflecting the electronwithdrawing property of the fluorine substituents.",

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doi = "10.1246/bcsj.82.1506",

language = "English",

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pages = "1506--1509",

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T1 - 197Au Mössbauer spectroscopic studies of cyclometalated golddimers containing 2-C6F4PPh2 ligands

AU - Bennett, Martin A.

AU - Mirzadeh, Nedaossadat

AU - Privér, Steven H.

AU - Takahashi, Masashi

AU - Bhargava, Suresh K.

PY - 2009

Y1 - 2009

N2 - 197Au Móssbauer spectra have been measured on a series of homovalent and heterovalent dinuclear gold complexes containing the 2-C 6F4PPh2 ligand. The correlation plot indicates that the electron densities of the 6s and 6p orbitalsof the gold atoms in these complexes are less than those of their protio and 6-methyl analogs, reflecting the electronwithdrawing property of the fluorine substituents.

AB - 197Au Móssbauer spectra have been measured on a series of homovalent and heterovalent dinuclear gold complexes containing the 2-C 6F4PPh2 ligand. The correlation plot indicates that the electron densities of the 6s and 6p orbitalsof the gold atoms in these complexes are less than those of their protio and 6-methyl analogs, reflecting the electronwithdrawing property of the fluorine substituents.

UR - https://www.scopus.com/pages/publications/73249147420

U2 - 10.1246/bcsj.82.1506

DO - 10.1246/bcsj.82.1506

M3 - Article

SN - 0009-2673

VL - 82

SP - 1506

EP - 1509

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 12

ER -

¹⁹⁷Au Mössbauer spectroscopic studies of cyclometalated golddimers containing 2-C₆F₄PPh₂ ligands

Abstract

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