197Au Mössbauer spectroscopic study of binuclear cycloaurated complexes containing bridging (2-diphenylarsino-n-methyl)phenyl (n = 5 and 6)

Kunihiko Kitadai, Masashi Takahashi, Masuo Takeda*, Suresh K. Bhargava, Martin A. Bennett

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    4 Citations (Scopus)

    Abstract

    197Au Mössbauer spectra have been measured on a series of binuclear gold complexes containing a bridging As-C ligand. The plot of quadrupole splitting (Q.S.) against isomer shift (I.S.) indicates that the gold-arsenic bond in these complexes is less covalent than the gold-phosphorus bond in analogous P-C complexes.

    Original languageEnglish
    Pages (from-to)886-888
    Number of pages3
    JournalBulletin of the Chemical Society of Japan
    Volume79
    Issue number6
    DOIs
    Publication statusPublished - 2006

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