197Au Mössbauer spectroscopic study of binuclear cycloaurated complexes containing bridging (2-diphenylarsino-n-methyl)phenyl (n = 5 and 6)

Kunihiko Kitadai; Masashi Takahashi; Masuo Takeda; Suresh K. Bhargava; Martin A. Bennett

doi:10.1246/bcsj.79.886

¹⁹⁷Au Mössbauer spectroscopic study of binuclear cycloaurated complexes containing bridging (2-diphenylarsino-n-methyl)phenyl (n = 5 and 6)

Kunihiko Kitadai, Masashi Takahashi, Masuo Takeda^*, Suresh K. Bhargava, Martin A. Bennett

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

¹⁹⁷Au Mössbauer spectra have been measured on a series of binuclear gold complexes containing a bridging As-C ligand. The plot of quadrupole splitting (Q.S.) against isomer shift (I.S.) indicates that the gold-arsenic bond in these complexes is less covalent than the gold-phosphorus bond in analogous P-C complexes.

Original language	English
Pages (from-to)	886-888
Number of pages	3
Journal	Bulletin of the Chemical Society of Japan
Volume	79
Issue number	6
DOIs	https://doi.org/10.1246/bcsj.79.886
Publication status	Published - 2006

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10.1246/bcsj.79.886

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title = "197Au M{\"o}ssbauer spectroscopic study of binuclear cycloaurated complexes containing bridging (2-diphenylarsino-n-methyl)phenyl (n = 5 and 6)",

abstract = "197Au M{\"o}ssbauer spectra have been measured on a series of binuclear gold complexes containing a bridging As-C ligand. The plot of quadrupole splitting (Q.S.) against isomer shift (I.S.) indicates that the gold-arsenic bond in these complexes is less covalent than the gold-phosphorus bond in analogous P-C complexes.",

author = "Kunihiko Kitadai and Masashi Takahashi and Masuo Takeda and Bhargava, \{Suresh K.\} and Bennett, \{Martin A.\}",

year = "2006",

doi = "10.1246/bcsj.79.886",

language = "English",

volume = "79",

pages = "886--888",

journal = "Bulletin of the Chemical Society of Japan",

issn = "0009-2673",

publisher = "Oxford University Press ",

number = "6",

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T1 - 197Au Mössbauer spectroscopic study of binuclear cycloaurated complexes containing bridging (2-diphenylarsino-n-methyl)phenyl (n = 5 and 6)

AU - Kitadai, Kunihiko

AU - Takahashi, Masashi

AU - Takeda, Masuo

AU - Bhargava, Suresh K.

AU - Bennett, Martin A.

PY - 2006

Y1 - 2006

N2 - 197Au Mössbauer spectra have been measured on a series of binuclear gold complexes containing a bridging As-C ligand. The plot of quadrupole splitting (Q.S.) against isomer shift (I.S.) indicates that the gold-arsenic bond in these complexes is less covalent than the gold-phosphorus bond in analogous P-C complexes.

AB - 197Au Mössbauer spectra have been measured on a series of binuclear gold complexes containing a bridging As-C ligand. The plot of quadrupole splitting (Q.S.) against isomer shift (I.S.) indicates that the gold-arsenic bond in these complexes is less covalent than the gold-phosphorus bond in analogous P-C complexes.

UR - https://www.scopus.com/pages/publications/33750597183

U2 - 10.1246/bcsj.79.886

DO - 10.1246/bcsj.79.886

M3 - Article

SN - 0009-2673

VL - 79

SP - 886

EP - 888

JO - Bulletin of the Chemical Society of Japan

JF - Bulletin of the Chemical Society of Japan

IS - 6

ER -

¹⁹⁷Au Mössbauer spectroscopic study of binuclear cycloaurated complexes containing bridging (2-diphenylarsino-n-methyl)phenyl (n = 5 and 6)

Abstract

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