Switching the cubic nonlinear optical properties of an electro-, halo-, and photochromic ruthenium alkynyl complex across six states

Katy A. Green; Marie P. Cifuentes; T. Christopher Corkery; Marek Samoc; Mark G. Humphrey

doi:10.1002/anie.200903027

Switching the cubic nonlinear optical properties of an electro-, halo-, and photochromic ruthenium alkynyl complex across six states

Katy A. Green
, Marie P. Cifuentes
, T. Christopher Corkery
, Marek Samoc
, Mark G. Humphrey

Research output: Contribution to journal › Article › peer-review

153 Citations (Scopus)

Abstract

More than on and off: The title complex (see picture) comprises addressable modules that respond independently to protic (alkynyl ligand⇄vinylidene ligand), electrochemical (metal-centered redox: Ru^II⇄Ru ^III), and photochemical (dithienylperfluorocyclopentene ring-opening⇄ring-closing) stimuli. The six states are interconverted along seven pathways, all of which result in distinct changes to cubic nonlinearity.

Original language	English
Pages (from-to)	7867-7870
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	42
DOIs	https://doi.org/10.1002/anie.200903027
Publication status	Published - 5 Oct 2009

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title = "Switching the cubic nonlinear optical properties of an electro-, halo-, and photochromic ruthenium alkynyl complex across six states",

abstract = "More than on and off: The title complex (see picture) comprises addressable modules that respond independently to protic (alkynyl ligand⇄vinylidene ligand), electrochemical (metal-centered redox: RuII⇄Ru III), and photochemical (dithienylperfluorocyclopentene ring-opening⇄ring-closing) stimuli. The six states are interconverted along seven pathways, all of which result in distinct changes to cubic nonlinearity.",

keywords = "Alkynyl complexes, Molecular devices, Nonlinear absorption, Nonlinear optics, Organometallics",

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doi = "10.1002/anie.200903027",

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T1 - Switching the cubic nonlinear optical properties of an electro-, halo-, and photochromic ruthenium alkynyl complex across six states

AU - Green, Katy A.

AU - Cifuentes, Marie P.

AU - Corkery, T. Christopher

AU - Samoc, Marek

AU - Humphrey, Mark G.

PY - 2009/10/5

Y1 - 2009/10/5

N2 - More than on and off: The title complex (see picture) comprises addressable modules that respond independently to protic (alkynyl ligand⇄vinylidene ligand), electrochemical (metal-centered redox: RuII⇄Ru III), and photochemical (dithienylperfluorocyclopentene ring-opening⇄ring-closing) stimuli. The six states are interconverted along seven pathways, all of which result in distinct changes to cubic nonlinearity.

AB - More than on and off: The title complex (see picture) comprises addressable modules that respond independently to protic (alkynyl ligand⇄vinylidene ligand), electrochemical (metal-centered redox: RuII⇄Ru III), and photochemical (dithienylperfluorocyclopentene ring-opening⇄ring-closing) stimuli. The six states are interconverted along seven pathways, all of which result in distinct changes to cubic nonlinearity.

KW - Alkynyl complexes

KW - Molecular devices

KW - Nonlinear absorption

KW - Nonlinear optics

KW - Organometallics

UR - https://www.scopus.com/pages/publications/70349675504

U2 - 10.1002/anie.200903027

DO - 10.1002/anie.200903027

M3 - Article

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VL - 48

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EP - 7870

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 42

ER -

Switching the cubic nonlinear optical properties of an electro-, halo-, and photochromic ruthenium alkynyl complex across six states

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