Synthesis and catalytic application of [Rh(PPh3)(2)([9]aneS(3))]PF6

Anthony F. Hill; James D.E.T. Wilton-Ely

doi:10.1021/om970578q

Synthesis and catalytic application of [Rh(PPh3)(2)([9]aneS(3))]PF6

Anthony F. Hill^*, James D.E.T. Wilton-Ely

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The reaction of [RhCl(PPh3)(3)] with [9]aneS(3) (1,4,7-trithiacyclononane) and NH4PF6 provides [Rh(PPh3)(2)([9]aneS(3))]PF6, which undergoes ligand subsitution and oxidative-addition reactions and effectively catalyzes the demercuration of bis(alkynyl)mercurials.

Original language	English
Pages (from-to)	4517-4518
Number of pages	2
Journal	Organometallics
Volume	16
Issue number	21
DOIs	https://doi.org/10.1021/om970578q
Publication status	Published - 14 Oct 1997
Externally published	Yes

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title = "Synthesis and catalytic application of [Rh(PPh3)(2)([9]aneS(3))]PF6",

abstract = "The reaction of [RhCl(PPh3)(3)] with [9]aneS(3) (1,4,7-trithiacyclononane) and NH4PF6 provides [Rh(PPh3)(2)([9]aneS(3))]PF6, which undergoes ligand subsitution and oxidative-addition reactions and effectively catalyzes the demercuration of bis(alkynyl)mercurials.",

keywords = "Organometallic macrocycle chemistry, <9>anes3 = 1,4,7-trithiacyclononane, Complexes, 1,4,8,11-tetrathiacyclotetradecane, Rucl2(pph3)3, Rhodium(i), Ligands",

author = "Hill, {Anthony F.} and Wilton-Ely, {James D.E.T.}",

year = "1997",

month = oct,

day = "14",

doi = "10.1021/om970578q",

language = "English",

volume = "16",

pages = "4517--4518",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Synthesis and catalytic application of [Rh(PPh3)(2)([9]aneS(3))]PF6

AU - Hill, Anthony F.

AU - Wilton-Ely, James D.E.T.

PY - 1997/10/14

Y1 - 1997/10/14

N2 - The reaction of [RhCl(PPh3)(3)] with [9]aneS(3) (1,4,7-trithiacyclononane) and NH4PF6 provides [Rh(PPh3)(2)([9]aneS(3))]PF6, which undergoes ligand subsitution and oxidative-addition reactions and effectively catalyzes the demercuration of bis(alkynyl)mercurials.

AB - The reaction of [RhCl(PPh3)(3)] with [9]aneS(3) (1,4,7-trithiacyclononane) and NH4PF6 provides [Rh(PPh3)(2)([9]aneS(3))]PF6, which undergoes ligand subsitution and oxidative-addition reactions and effectively catalyzes the demercuration of bis(alkynyl)mercurials.

KW - Organometallic macrocycle chemistry

KW - <9>anes3 = 1,4,7-trithiacyclononane

KW - Complexes

KW - 1,4,8,11-tetrathiacyclotetradecane

KW - Rucl2(pph3)3

KW - Rhodium(i)

KW - Ligands

UR - http://www.scopus.com/inward/record.url?scp=0037759138&partnerID=8YFLogxK

U2 - 10.1021/om970578q

DO - 10.1021/om970578q

M3 - Article

AN - SCOPUS:0037759138

SN - 0276-7333

VL - 16

SP - 4517

EP - 4518

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Synthesis and catalytic application of [Rh(PPh3)(2)([9]aneS(3))]PF6

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