Synthesis and crystal structure of [Mo2FePt(μ-σ,σ′,σ″:η5-CC5H4)2(CO)4{HB(pz)3}2][HB(pz)3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1′-ferrocene derivative with CMo(CO)2{HB(pz)3} substituents

Simon J. Davies; Anthony F. Hill; Massimino U. Pilotti; F. Gordon A. Stone

doi:10.1016/S0277-5387(00)81253-X

Synthesis and crystal structure of [Mo₂FePt(μ-σ,σ′,σ″:η⁵-CC₅H₄)₂(CO)₄{HB(pz)₃}2][HB(pz)₃ = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1′-ferrocene derivative with CMo(CO)₂{HB(pz)₃} substituents

Simon J. Davies, Anthony F. Hill, Massimino U. Pilotti, F. Gordon A. Stone^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Treatment of [Mo(CO)₆] in tetrahydrofuran, with 1,1′-dilithioferrocene in light petroleum, followed by (CF₃CO)₂O and tmeda (Me₂NCH₂CH₂NMe₂) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo₂Fe(μ-σ, σ′,:η⁵-CC₅H₄)₂(O₂CCF₃)₂ (CO)₄(tmeda)₂]. The latter with K[HB(pz)₃] [HB(pz)₃ = hydrotris(pyrazol-1-yl)borate] in CH₂Cl₂ gives [Mo₂Fe(μ-σ,σ′:gh⁵ -CC₅H₄)₂(CO)₄{HB(pz)₃}₂], which with [Pt(cod)₂] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo₂FePt(μ-σ,σ′,δ″:η⁵-CC₅H₄)₂(CO)₄{HB(pz)₃}₂]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand.

Original language	English
Pages (from-to)	2265-2270
Number of pages	6
Journal	Polyhedron
Volume	8
Issue number	18
DOIs	https://doi.org/10.1016/S0277-5387(00)81253-X
Publication status	Published - 1989
Externally published	Yes

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@article{acfba2fd2a904e2e97d0ba5406ff060e,

title = "Synthesis and crystal structure of [Mo2FePt(μ-σ,σ′,σ″:η5-CC5H4)2(CO)4{HB(pz)3}2][HB(pz)3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1′-ferrocene derivative with CMo(CO)2{HB(pz)3} substituents",

abstract = "Treatment of [Mo(CO)6] in tetrahydrofuran, with 1,1′-dilithioferrocene in light petroleum, followed by (CF3CO)2O and tmeda (Me2NCH2CH2NMe2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo2Fe(μ-σ, σ′,:η5-CC5H4)2(O2CCF3)2 (CO)4(tmeda)2]. The latter with K[HB(pz)3] [HB(pz)3 = hydrotris(pyrazol-1-yl)borate] in CH2Cl2 gives [Mo2Fe(μ-σ,σ′:gh5 -CC5H4)2(CO)4{HB(pz)3}2], which with [Pt(cod)2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo2FePt(μ-σ,σ′,δ″:η5-CC5H4)2(CO)4{HB(pz)3}2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand.",

author = "Davies, {Simon J.} and Hill, {Anthony F.} and Pilotti, {Massimino U.} and {A. Stone}, {F. Gordon}",

year = "1989",

doi = "10.1016/S0277-5387(00)81253-X",

language = "English",

volume = "8",

pages = "2265--2270",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "18",

}

Synthesis and crystal structure of [Mo₂FePt(μ-σ,σ′,σ″:η⁵-CC₅H₄)₂(CO)₄{HB(pz)₃}2][HB(pz)₃ = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1′-ferrocene derivative with CMo(CO)₂{HB(pz)₃} substituents. / Davies, Simon J.; Hill, Anthony F.; Pilotti, Massimino U. et al.
In: Polyhedron, Vol. 8, No. 18, 1989, p. 2265-2270.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and crystal structure of [Mo2FePt(μ-σ,σ′,σ″:η5-CC5H4)2(CO)4{HB(pz)3}2][HB(pz)3 = Hydrotris(pyrazol-1-yl)borate]; A complex derived from a 1,1′-ferrocene derivative with CMo(CO)2{HB(pz)3} substituents

AU - Davies, Simon J.

AU - Hill, Anthony F.

AU - Pilotti, Massimino U.

AU - A. Stone, F. Gordon

PY - 1989

Y1 - 1989

N2 - Treatment of [Mo(CO)6] in tetrahydrofuran, with 1,1′-dilithioferrocene in light petroleum, followed by (CF3CO)2O and tmeda (Me2NCH2CH2NMe2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo2Fe(μ-σ, σ′,:η5-CC5H4)2(O2CCF3)2 (CO)4(tmeda)2]. The latter with K[HB(pz)3] [HB(pz)3 = hydrotris(pyrazol-1-yl)borate] in CH2Cl2 gives [Mo2Fe(μ-σ,σ′:gh5 -CC5H4)2(CO)4{HB(pz)3}2], which with [Pt(cod)2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo2FePt(μ-σ,σ′,δ″:η5-CC5H4)2(CO)4{HB(pz)3}2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand.

AB - Treatment of [Mo(CO)6] in tetrahydrofuran, with 1,1′-dilithioferrocene in light petroleum, followed by (CF3CO)2O and tmeda (Me2NCH2CH2NMe2) affords the ferrocene- substituted bis(alkylidynemolybdenum) complex [Mo2Fe(μ-σ, σ′,:η5-CC5H4)2(O2CCF3)2 (CO)4(tmeda)2]. The latter with K[HB(pz)3] [HB(pz)3 = hydrotris(pyrazol-1-yl)borate] in CH2Cl2 gives [Mo2Fe(μ-σ,σ′:gh5 -CC5H4)2(CO)4{HB(pz)3}2], which with [Pt(cod)2] (cod = cyclo-octa-1,5-diene), in light petroleum saturated with ethylene, yields the tetranuclear metal complex [Mo2FePt(μ-σ,σ′,δ″:η5-CC5H4)2(CO)4{HB(pz)3}2]. The structure of this product was established by X-ray diffraction, and the results of this study are compared with those obtained for related compounds in which the two metal-metal bonds of an acyclic trimetal system, in this case MoPtMo, are each spanned by an alkylidyne group and semi-bridged by a carbonyl ligand.

UR - http://www.scopus.com/inward/record.url?scp=0008119341&partnerID=8YFLogxK

U2 - 10.1016/S0277-5387(00)81253-X

DO - 10.1016/S0277-5387(00)81253-X

M3 - Article

AN - SCOPUS:0008119341

SN - 0277-5387

VL - 8

SP - 2265

EP - 2270

JO - Polyhedron

JF - Polyhedron

IS - 18

ER -