Synthesis and electrochemistry of [Pt(tame)2]4+ crystallographic analysis of bis[1,1,1-tris(aminomethyl)ethane-N,N′]platinum(II) bis(tetrachlorozincate) dihydrate

Kylie N. Brown; David C.R. Hockless; Alan M. Sargeson

doi:10.1039/a901725i

Synthesis and electrochemistry of [Pt(tame)₂]⁴⁺ crystallographic analysis of bis[1,1,1-tris(aminomethyl)ethane-N,N′]platinum(II) bis(tetrachlorozincate) dihydrate

Kylie N. Brown, David C.R. Hockless, Alan M. Sargeson

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Reaction of K₂PtCl₆ with the tripodal ligand tame [1,1,1-tris(aminomethyl)ethane] in dimethylformamide catalysed by K₂PtCl₄ afforded the octahedral bis(tridentate ligand) [Pt(tame)₂]⁴⁺ ion. The cyclic voltammogram of [Pt(tame)₂]⁴⁺ in aqueous media showed an irreversible reduction of the six-co-ordinate platinum(IV) species to Pt^II and bulk electrochemical reduction of the [Pt^IV(tame)₂]⁴⁺ ion quantitatively produced a square planar platinum(II) complex [Pt(tame)₂]²⁺. Crystallographic analysis of the protonated complex [Pt^II(Htame)₂][ZnCl₄] ₂·2H₂O, showed two dissociated nitrogen atoms on opposite sides of the PtN₄²⁺ co-ordination plane which has typical Pt^II-N bond lengths (2.042(6) Å). The routes to the formation of the [Pt^IV(tame)₂]⁴⁺ ion and its reduced product are addressed.

Original language	English
Pages (from-to)	2171-2175
Number of pages	5
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	13
DOIs	https://doi.org/10.1039/a901725i
Publication status	Published - 1999

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title = "Synthesis and electrochemistry of [Pt(tame)2]4+ crystallographic analysis of bis[1,1,1-tris(aminomethyl)ethane-N,N′]platinum(II) bis(tetrachlorozincate) dihydrate",

abstract = "Reaction of K2PtCl6 with the tripodal ligand tame [1,1,1-tris(aminomethyl)ethane] in dimethylformamide catalysed by K2PtCl4 afforded the octahedral bis(tridentate ligand) [Pt(tame)2]4+ ion. The cyclic voltammogram of [Pt(tame)2]4+ in aqueous media showed an irreversible reduction of the six-co-ordinate platinum(IV) species to PtII and bulk electrochemical reduction of the [PtIV(tame)2]4+ ion quantitatively produced a square planar platinum(II) complex [Pt(tame)2]2+. Crystallographic analysis of the protonated complex [PtII(Htame)2][ZnCl4] 2·2H2O, showed two dissociated nitrogen atoms on opposite sides of the PtN42+ co-ordination plane which has typical PtII-N bond lengths (2.042(6) {\AA}). The routes to the formation of the [PtIV(tame)2]4+ ion and its reduced product are addressed.",

author = "Brown, {Kylie N.} and Hockless, {David C.R.} and Sargeson, {Alan M.}",

year = "1999",

doi = "10.1039/a901725i",

language = "English",

pages = "2171--2175",

journal = "Journal of the Chemical Society. Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "13",

}

Synthesis and electrochemistry of [Pt(tame)₂]⁴⁺ crystallographic analysis of bis[1,1,1-tris(aminomethyl)ethane-N,N′]platinum(II) bis(tetrachlorozincate) dihydrate. / Brown, Kylie N.; Hockless, David C.R.; Sargeson, Alan M.
In: Journal of the Chemical Society. Dalton Transactions, No. 13, 1999, p. 2171-2175.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and electrochemistry of [Pt(tame)2]4+ crystallographic analysis of bis[1,1,1-tris(aminomethyl)ethane-N,N′]platinum(II) bis(tetrachlorozincate) dihydrate

AU - Brown, Kylie N.

AU - Hockless, David C.R.

AU - Sargeson, Alan M.

PY - 1999

Y1 - 1999

N2 - Reaction of K2PtCl6 with the tripodal ligand tame [1,1,1-tris(aminomethyl)ethane] in dimethylformamide catalysed by K2PtCl4 afforded the octahedral bis(tridentate ligand) [Pt(tame)2]4+ ion. The cyclic voltammogram of [Pt(tame)2]4+ in aqueous media showed an irreversible reduction of the six-co-ordinate platinum(IV) species to PtII and bulk electrochemical reduction of the [PtIV(tame)2]4+ ion quantitatively produced a square planar platinum(II) complex [Pt(tame)2]2+. Crystallographic analysis of the protonated complex [PtII(Htame)2][ZnCl4] 2·2H2O, showed two dissociated nitrogen atoms on opposite sides of the PtN42+ co-ordination plane which has typical PtII-N bond lengths (2.042(6) Å). The routes to the formation of the [PtIV(tame)2]4+ ion and its reduced product are addressed.

AB - Reaction of K2PtCl6 with the tripodal ligand tame [1,1,1-tris(aminomethyl)ethane] in dimethylformamide catalysed by K2PtCl4 afforded the octahedral bis(tridentate ligand) [Pt(tame)2]4+ ion. The cyclic voltammogram of [Pt(tame)2]4+ in aqueous media showed an irreversible reduction of the six-co-ordinate platinum(IV) species to PtII and bulk electrochemical reduction of the [PtIV(tame)2]4+ ion quantitatively produced a square planar platinum(II) complex [Pt(tame)2]2+. Crystallographic analysis of the protonated complex [PtII(Htame)2][ZnCl4] 2·2H2O, showed two dissociated nitrogen atoms on opposite sides of the PtN42+ co-ordination plane which has typical PtII-N bond lengths (2.042(6) Å). The routes to the formation of the [PtIV(tame)2]4+ ion and its reduced product are addressed.

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U2 - 10.1039/a901725i

DO - 10.1039/a901725i

M3 - Article

SN - 1470-479X

SP - 2171

EP - 2175

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 13

ER -

Synthesis and electrochemistry of [Pt(tame)₂]⁴⁺ crystallographic analysis of bis[1,1,1-tris(aminomethyl)ethane-N,N′]platinum(II) bis(tetrachlorozincate) dihydrate

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