Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule

Sebastian Leubner; Viktor E.G. Bengtsson; Kevin Synnatschke; Jonas Gosch; Alexander Koch; Helge Reinsch; Hongyi Xu; Claudia Backes; Xiaodong Zou; Norbert Stock

doi:10.1021/jacs.0c06978

Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule

Sebastian Leubner, Viktor E.G. Bengtsson, Kevin Synnatschke, Jonas Gosch, Alexander Koch, Helge Reinsch, Hongyi Xu, Claudia Backes, Xiaodong Zou^*, Norbert Stock^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Citations (SciVal)

Abstract

A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- A nd dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.

Original language	English
Pages (from-to)	15995-16000
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	142
Issue number	37
Early online date	21 Aug 2020
DOIs	https://doi.org/10.1021/jacs.0c06978
Publication status	Published - 16 Sept 2020
Externally published	Yes

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10.1021/jacs.0c06978

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Leubner, S., Bengtsson, V. E. G., Synnatschke, K., Gosch, J., Koch, A., Reinsch, H., Xu, H., Backes, C., Zou, X., & Stock, N. (2020). Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule. Journal of the American Chemical Society, 142(37), 15995-16000. https://doi.org/10.1021/jacs.0c06978

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title = "Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule",

abstract = "A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- A nd dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.",

author = "Sebastian Leubner and Bengtsson, {Viktor E.G.} and Kevin Synnatschke and Jonas Gosch and Alexander Koch and Helge Reinsch and Hongyi Xu and Claudia Backes and Xiaodong Zou and Norbert Stock",

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year = "2020",

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doi = "10.1021/jacs.0c06978",

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Leubner, S, Bengtsson, VEG, Synnatschke, K, Gosch, J, Koch, A, Reinsch, H, Xu, H, Backes, C, Zou, X & Stock, N 2020, 'Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule', Journal of the American Chemical Society, vol. 142, no. 37, pp. 15995-16000. https://doi.org/10.1021/jacs.0c06978

Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule. / Leubner, Sebastian; Bengtsson, Viktor E.G.; Synnatschke, Kevin et al.
In: Journal of the American Chemical Society, Vol. 142, No. 37, 16.09.2020, p. 15995-16000.

Research output: Contribution to journal › Article › peer-review

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T1 - Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule

AU - Leubner, Sebastian

AU - Bengtsson, Viktor E.G.

AU - Synnatschke, Kevin

AU - Gosch, Jonas

AU - Koch, Alexander

AU - Reinsch, Helge

AU - Xu, Hongyi

AU - Backes, Claudia

AU - Zou, Xiaodong

AU - Stock, Norbert

PY - 2020/9/16

Y1 - 2020/9/16

N2 - A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)26(OAc)18L18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- A nd dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.

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Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- A nd Dodecanuclear Clusters as Well as a Small Organic Linker Molecule

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