Synthesis and ligand substitution reactions of κ                         4                         -B,S,S′,S′′-ruthenaboratranes

Mark R.St J. Foreman; Anthony F. Hill; Chenxi Ma; Never Tshabang; Andrew J.P. White

doi:10.1039/c8dt04278k

Synthesis and ligand substitution reactions of κ ⁴ -B,S,S′,S′′-ruthenaboratranes

Mark R.St J. Foreman, Anthony F. Hill^*, Chenxi Ma, Never Tshabang, Andrew J.P. White

^*Corresponding author for this work

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Abstract

A range of ruthenaboratranes of the form [Ru(CO)L{κ ⁴ -B,S,S′,S′′-B(mt) ₃ }] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh ₃ ligand in [Ru(CO)(PPh ₃ ){κ ⁴ -B,S,S′,S′′-B(mt) ₃ }] by L (L = PMe ₂ Ph, PMe ₃ , P(OMe) ₃ , P(OEt) ₃ , P(OPh) ₃ ) or reactions of [RuCl(R)(CO)L _n ] (R = Ph, CH═CHPh; n = 2, L = PCy ₃ ; n = 3, L = P(OMe) ₃ , PMe ₂ Ph) with Na[HB(mt) ₃ ].

Original language	English
Pages (from-to)	209-219
Number of pages	11
Journal	Dalton Transactions
Volume	48
Issue number	1
DOIs	https://doi.org/10.1039/c8dt04278k
Publication status	Published - 2019

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@article{78e48f6ac7034002bf41a07961ae9f34,

title = " Synthesis and ligand substitution reactions of κ 4 -B,S,S′,S′′-ruthenaboratranes ",

abstract = " A range of ruthenaboratranes of the form [Ru(CO)L{κ 4 -B,S,S′,S′′-B(mt) 3 }] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh 3 ligand in [Ru(CO)(PPh 3 ){κ 4 -B,S,S′,S′′-B(mt) 3 }] by L (L = PMe 2 Ph, PMe 3 , P(OMe) 3 , P(OEt) 3 , P(OPh) 3 ) or reactions of [RuCl(R)(CO)L n ] (R = Ph, CH═CHPh; n = 2, L = PCy 3 ; n = 3, L = P(OMe) 3 , PMe 2 Ph) with Na[HB(mt) 3 ].",

author = "Foreman, {Mark R.St J.} and Hill, {Anthony F.} and Chenxi Ma and Never Tshabang and White, {Andrew J.P.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8dt04278k",

language = "English",

volume = "48",

pages = "209--219",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "1",

}

Synthesis and ligand substitution reactions of κ ⁴ -B,S,S′,S′′-ruthenaboratranes . / Foreman, Mark R.St J.; Hill, Anthony F.; Ma, Chenxi et al.
In: Dalton Transactions, Vol. 48, No. 1, 2019, p. 209-219.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and ligand substitution reactions of κ 4 -B,S,S′,S′′-ruthenaboratranes

AU - Foreman, Mark R.St J.

AU - Hill, Anthony F.

AU - Ma, Chenxi

AU - Tshabang, Never

AU - White, Andrew J.P.

PY - 2019

Y1 - 2019

N2 - A range of ruthenaboratranes of the form [Ru(CO)L{κ 4 -B,S,S′,S′′-B(mt) 3 }] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh 3 ligand in [Ru(CO)(PPh 3 ){κ 4 -B,S,S′,S′′-B(mt) 3 }] by L (L = PMe 2 Ph, PMe 3 , P(OMe) 3 , P(OEt) 3 , P(OPh) 3 ) or reactions of [RuCl(R)(CO)L n ] (R = Ph, CH═CHPh; n = 2, L = PCy 3 ; n = 3, L = P(OMe) 3 , PMe 2 Ph) with Na[HB(mt) 3 ].

AB - A range of ruthenaboratranes of the form [Ru(CO)L{κ 4 -B,S,S′,S′′-B(mt) 3 }] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh 3 ligand in [Ru(CO)(PPh 3 ){κ 4 -B,S,S′,S′′-B(mt) 3 }] by L (L = PMe 2 Ph, PMe 3 , P(OMe) 3 , P(OEt) 3 , P(OPh) 3 ) or reactions of [RuCl(R)(CO)L n ] (R = Ph, CH═CHPh; n = 2, L = PCy 3 ; n = 3, L = P(OMe) 3 , PMe 2 Ph) with Na[HB(mt) 3 ].

UR - http://www.scopus.com/inward/record.url?scp=85058724339&partnerID=8YFLogxK

U2 - 10.1039/c8dt04278k

DO - 10.1039/c8dt04278k

M3 - Article

SN - 1477-9226

VL - 48

SP - 209

EP - 219

JO - Dalton Transactions

JF - Dalton Transactions

IS - 1

ER -

Synthesis and ligand substitution reactions of κ ⁴ -B,S,S′,S′′-ruthenaboratranes

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