Synthesis and structure determination of three new 12β-hydroxy C20 gibberellins (GA127, GA128 and GA129)

Sarah K. Leitch; Patrick S. Blake; Lewis N. Mander

Synthesis and structure determination of three new 12β-hydroxy C₂₀ gibberellins (GA₁₂₇, GA₁₂₈ and GA₁₂₉)

Sarah K. Leitch, Patrick S. Blake, Lewis N. Mander^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Three new 12β-hydroxylated C₂₀ gibberellins have been isolated from strawberry fruitlets and their structures confirmed by synthesis from gibberellic acid. The key stages in the synthesis involved transannular hydroxylation using diacetoxy iodobenzene and oxidative cleavage of an enolate function by molecular oxygen.

Original language	English
Pages (from-to)	145-160
Number of pages	16
Journal	Arkivoc
Volume	2003
Issue number	7
Publication status	Published - 2003

Cite this

@article{aefe6dda270a4aa5ad49eeb0674d8e7e,

title = "Synthesis and structure determination of three new 12β-hydroxy C20 gibberellins (GA127, GA128 and GA129)",

abstract = "Three new 12β-hydroxylated C20 gibberellins have been isolated from strawberry fruitlets and their structures confirmed by synthesis from gibberellic acid. The key stages in the synthesis involved transannular hydroxylation using diacetoxy iodobenzene and oxidative cleavage of an enolate function by molecular oxygen.",

keywords = "Diacetoxy iodobenzene, Enolate, Gibberellin, Oxidative cleavage, Strawberry, Transannular hydroxylation",

author = "Leitch, {Sarah K.} and Blake, {Patrick S.} and Mander, {Lewis N.}",

year = "2003",

language = "English",

volume = "2003",

pages = "145--160",

journal = "Arkivoc",

issn = "1551-7004",

publisher = "Arkat USA",

number = "7",

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TY - JOUR

T1 - Synthesis and structure determination of three new 12β-hydroxy C20 gibberellins (GA127, GA128 and GA129)

AU - Leitch, Sarah K.

AU - Blake, Patrick S.

AU - Mander, Lewis N.

PY - 2003

Y1 - 2003

N2 - Three new 12β-hydroxylated C20 gibberellins have been isolated from strawberry fruitlets and their structures confirmed by synthesis from gibberellic acid. The key stages in the synthesis involved transannular hydroxylation using diacetoxy iodobenzene and oxidative cleavage of an enolate function by molecular oxygen.

AB - Three new 12β-hydroxylated C20 gibberellins have been isolated from strawberry fruitlets and their structures confirmed by synthesis from gibberellic acid. The key stages in the synthesis involved transannular hydroxylation using diacetoxy iodobenzene and oxidative cleavage of an enolate function by molecular oxygen.

KW - Diacetoxy iodobenzene

KW - Enolate

KW - Gibberellin

KW - Oxidative cleavage

KW - Strawberry

KW - Transannular hydroxylation

UR - http://www.scopus.com/inward/record.url?scp=3242668740&partnerID=8YFLogxK

M3 - Article

SN - 1551-7004

VL - 2003

SP - 145

EP - 160

JO - Arkivoc

JF - Arkivoc

IS - 7

ER -

Synthesis and structure determination of three new 12β-hydroxy C₂₀ gibberellins (GA₁₂₇, GA₁₂₈ and GA₁₂₉)

Abstract

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