Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core

Areej Merhi; Guillaume Grelaud; Mahbod Morshedi; Seyfallah Abid; Katy A. Green; Adam Barlow; Thomas Groizard; Samia Kahlal; Jean François Halet; Hoang Minh Ngo; Isabelle Ledoux; Marie P. Cifuentes; Mark G. Humphrey; Frédéric Paul; Christine O. Paul-Roth

doi:10.1039/c8dt02301h

Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core

Areej Merhi, Guillaume Grelaud, Mahbod Morshedi, Seyfallah Abid, Katy A. Green, Adam Barlow, Thomas Groizard, Samia Kahlal, Jean François Halet, Hoang Minh Ngo, Isabelle Ledoux, Marie P. Cifuentes, Mark G. Humphrey, Frédéric Paul^*, Christine O. Paul-Roth

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new Zn(ii) porphyrin-based dendrimer (5₂) containing twelve Ru(ii) alkynyl fragments, has been prepared following a convergent approach in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) (6). The cubic nonlinear optical (NLO) properties of 5₂ and other derivatives of 6 have been measured by third-harmonic generation (THG) at 1907 nm and by Z-scan over the spectral range 500-1700 nm, revealing the remarkable NLO response of 5₂ in the near-IR range. These results highlight the beneficial role of the extended "cross fourchée"-like polymetallic structure of 5₂ on its third-order NLO properties.

Original language	English
Pages (from-to)	11123-11135
Number of pages	13
Journal	Dalton Transactions
Volume	47
Issue number	32
DOIs	https://doi.org/10.1039/c8dt02301h
Publication status	Published - 2018

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Merhi, A., Grelaud, G., Morshedi, M., Abid, S., Green, K. A., Barlow, A., Groizard, T., Kahlal, S., Halet, J. F., Ngo, H. M., Ledoux, I., Cifuentes, M. P., Humphrey, M. G., Paul, F., & Paul-Roth, C. O. (2018). Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core. Dalton Transactions, 47(32), 11123-11135. https://doi.org/10.1039/c8dt02301h

@article{d3dfcb6514dc413db20dd9594437dc51,

title = "Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core",

abstract = "A new Zn(ii) porphyrin-based dendrimer (52) containing twelve Ru(ii) alkynyl fragments, has been prepared following a convergent approach in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) (6). The cubic nonlinear optical (NLO) properties of 52 and other derivatives of 6 have been measured by third-harmonic generation (THG) at 1907 nm and by Z-scan over the spectral range 500-1700 nm, revealing the remarkable NLO response of 52 in the near-IR range. These results highlight the beneficial role of the extended {"}cross fourch{\'e}e{"}-like polymetallic structure of 52 on its third-order NLO properties.",

author = "Areej Merhi and Guillaume Grelaud and Mahbod Morshedi and Seyfallah Abid and Green, {Katy A.} and Adam Barlow and Thomas Groizard and Samia Kahlal and Halet, {Jean Fran{\c c}ois} and Ngo, {Hoang Minh} and Isabelle Ledoux and Cifuentes, {Marie P.} and Humphrey, {Mark G.} and Fr{\'e}d{\'e}ric Paul and Paul-Roth, {Christine O.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2018.",

year = "2018",

doi = "10.1039/c8dt02301h",

language = "English",

volume = "47",

pages = "11123--11135",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "32",

}

Merhi, A, Grelaud, G, Morshedi, M, Abid, S, Green, KA, Barlow, A, Groizard, T, Kahlal, S, Halet, JF, Ngo, HM, Ledoux, I, Cifuentes, MP, Humphrey, MG, Paul, F & Paul-Roth, CO 2018, 'Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core', Dalton Transactions, vol. 47, no. 32, pp. 11123-11135. https://doi.org/10.1039/c8dt02301h

TY - JOUR

T1 - Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core

AU - Merhi, Areej

AU - Grelaud, Guillaume

AU - Morshedi, Mahbod

AU - Abid, Seyfallah

AU - Green, Katy A.

AU - Barlow, Adam

AU - Groizard, Thomas

AU - Kahlal, Samia

AU - Halet, Jean François

AU - Ngo, Hoang Minh

AU - Ledoux, Isabelle

AU - Cifuentes, Marie P.

AU - Humphrey, Mark G.

AU - Paul, Frédéric

AU - Paul-Roth, Christine O.

PY - 2018

Y1 - 2018

N2 - A new Zn(ii) porphyrin-based dendrimer (52) containing twelve Ru(ii) alkynyl fragments, has been prepared following a convergent approach in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) (6). The cubic nonlinear optical (NLO) properties of 52 and other derivatives of 6 have been measured by third-harmonic generation (THG) at 1907 nm and by Z-scan over the spectral range 500-1700 nm, revealing the remarkable NLO response of 52 in the near-IR range. These results highlight the beneficial role of the extended "cross fourchée"-like polymetallic structure of 52 on its third-order NLO properties.

AB - A new Zn(ii) porphyrin-based dendrimer (52) containing twelve Ru(ii) alkynyl fragments, has been prepared following a convergent approach in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) (6). The cubic nonlinear optical (NLO) properties of 52 and other derivatives of 6 have been measured by third-harmonic generation (THG) at 1907 nm and by Z-scan over the spectral range 500-1700 nm, revealing the remarkable NLO response of 52 in the near-IR range. These results highlight the beneficial role of the extended "cross fourchée"-like polymetallic structure of 52 on its third-order NLO properties.

UR - http://www.scopus.com/inward/record.url?scp=85051710083&partnerID=8YFLogxK

U2 - 10.1039/c8dt02301h

DO - 10.1039/c8dt02301h

M3 - Article

SN - 1477-9226

VL - 47

SP - 11123

EP - 11135

JO - Dalton Transactions

JF - Dalton Transactions

IS - 32

ER -

Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core

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