Synthesis of carbazoloquinone natural products 'on-water'

P. Norcott; C. S.P. McErlean

doi:10.1039/c5ob00852b

Synthesis of carbazoloquinone natural products 'on-water'

P. Norcott, C. S.P. McErlean^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The total synthesis of a number of carbazolo-1,4-quinone natural products using on-water chemistry is described. A recently developed domino 'in-water, on-water' process is employed to rapidly and efficiently generate königinequinone A, which subsequently enables access to murrayaquinones B, C, D and E, and pyrayaquinones B and C, via a remarkably facile on-water catalysed Claisen rearrangement.

Original language	English
Pages (from-to)	6866-6878
Number of pages	13
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	24
DOIs	https://doi.org/10.1039/c5ob00852b
Publication status	Published - 28 Jun 2015
Externally published	Yes

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abstract = "The total synthesis of a number of carbazolo-1,4-quinone natural products using on-water chemistry is described. A recently developed domino 'in-water, on-water' process is employed to rapidly and efficiently generate k{\"o}niginequinone A, which subsequently enables access to murrayaquinones B, C, D and E, and pyrayaquinones B and C, via a remarkably facile on-water catalysed Claisen rearrangement.",

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AB - The total synthesis of a number of carbazolo-1,4-quinone natural products using on-water chemistry is described. A recently developed domino 'in-water, on-water' process is employed to rapidly and efficiently generate königinequinone A, which subsequently enables access to murrayaquinones B, C, D and E, and pyrayaquinones B and C, via a remarkably facile on-water catalysed Claisen rearrangement.

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EP - 6878

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Synthesis of carbazoloquinone natural products 'on-water'

Abstract

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