Synthesis of heterobimetallic telluro - Acyl complexes

Basiiir A. Nasir; Anthony F. Hill; F. Gordon A. Stone

Synthesis of heterobimetallic telluro - Acyl complexes

Basiiir A. Nasir, Anthony F. Hill, F. Gordon A. Stone

Research School of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The μ-alkylidene dimetal complexes [M Fe (μ - C₆H ₃Me₂ - 2, 6) (CO)₅, (ν -C₅H ₅)], (M = Cr, Mo or W) reacted with elemental tellurium yielding the heterobimetallic compounds [M Fe (μ, - ν)² - Te CC ₆H₃ Me₂-2, 6) (CO)₅ (ν - C ₅H₅)]. Similarly, the reaction between [Mo Fe(μ - CC₆ H₄ Me - 4) (CO)₅ (ν - C ₅H₅)] and tellurium afforded the complex (MoFe μ - ν)² - Te C C₆H₄ Me-4)(CO) ₅(ν-C₅H₅)].

Original language	English
Pages (from-to)	27-30
Number of pages	4
Journal	Journal of the Chemical Society of Pakistan
Volume	19
Issue number	1
Publication status	Published - 1997

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@article{e748171f0e934ba4bba0a5e2a6cafc75,

title = "Synthesis of heterobimetallic telluro - Acyl complexes",

abstract = "The μ-alkylidene dimetal complexes [M Fe (μ - C6H 3Me2 - 2, 6) (CO)5, (ν -C5H 5)], (M = Cr, Mo or W) reacted with elemental tellurium yielding the heterobimetallic compounds [M Fe (μ, - ν)2 - Te CC 6H3 Me2-2, 6) (CO)5 (ν - C 5H5)]. Similarly, the reaction between [Mo Fe(μ - CC6 H4 Me - 4) (CO)5 (ν - C 5H5)] and tellurium afforded the complex (MoFe μ - ν)2 - Te C C6H4 Me-4)(CO) 5(ν-C5H5)].",

author = "Nasir, {Basiiir A.} and Hill, {Anthony F.} and Stone, {F. Gordon A.}",

year = "1997",

language = "English",

volume = "19",

pages = "27--30",

journal = "Journal of the Chemical Society of Pakistan",

issn = "0253-5106",

publisher = "Chemical Society of Pakistan",

number = "1",

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TY - JOUR

T1 - Synthesis of heterobimetallic telluro - Acyl complexes

AU - Nasir, Basiiir A.

AU - Hill, Anthony F.

AU - Stone, F. Gordon A.

PY - 1997

Y1 - 1997

N2 - The μ-alkylidene dimetal complexes [M Fe (μ - C6H 3Me2 - 2, 6) (CO)5, (ν -C5H 5)], (M = Cr, Mo or W) reacted with elemental tellurium yielding the heterobimetallic compounds [M Fe (μ, - ν)2 - Te CC 6H3 Me2-2, 6) (CO)5 (ν - C 5H5)]. Similarly, the reaction between [Mo Fe(μ - CC6 H4 Me - 4) (CO)5 (ν - C 5H5)] and tellurium afforded the complex (MoFe μ - ν)2 - Te C C6H4 Me-4)(CO) 5(ν-C5H5)].

AB - The μ-alkylidene dimetal complexes [M Fe (μ - C6H 3Me2 - 2, 6) (CO)5, (ν -C5H 5)], (M = Cr, Mo or W) reacted with elemental tellurium yielding the heterobimetallic compounds [M Fe (μ, - ν)2 - Te CC 6H3 Me2-2, 6) (CO)5 (ν - C 5H5)]. Similarly, the reaction between [Mo Fe(μ - CC6 H4 Me - 4) (CO)5 (ν - C 5H5)] and tellurium afforded the complex (MoFe μ - ν)2 - Te C C6H4 Me-4)(CO) 5(ν-C5H5)].

UR - http://www.scopus.com/inward/record.url?scp=0348149862&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0348149862

SN - 0253-5106

VL - 19

SP - 27

EP - 30

JO - Journal of the Chemical Society of Pakistan

JF - Journal of the Chemical Society of Pakistan

IS - 1

ER -

Synthesis of heterobimetallic telluro - Acyl complexes

Abstract

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