Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

Philip Norcott; Christopher S.P. McErlean

doi:10.1071/CH18019

Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

Philip Norcott, Christopher S.P. McErlean^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.

Original language	English
Pages (from-to)	366-372
Number of pages	7
Journal	Australian Journal of Chemistry
Volume	71
Issue number	5
DOIs	https://doi.org/10.1071/CH18019
Publication status	Published - 2018
Externally published	Yes

Access to Document

10.1071/CH18019

Cite this

@article{7bc9cef60bb348a8988ee0c144064ca8,

title = "Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement",

abstract = "Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.",

author = "Philip Norcott and McErlean, {Christopher S.P.}",

note = "Publisher Copyright: {\textcopyright} CSIRO.",

year = "2018",

doi = "10.1071/CH18019",

language = "English",

volume = "71",

pages = "366--372",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO",

number = "5",

}

TY - JOUR

T1 - Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

AU - Norcott, Philip

AU - McErlean, Christopher S.P.

N1 - Publisher Copyright: © CSIRO.

PY - 2018

Y1 - 2018

N2 - Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.

AB - Computational methods were used to investigate the stereochemical course of the extra-annular Claisen rearrangement. The stereochemical fidelity of the synthetic strategy and comparison of the optical properties support the hypothesis that the heliespirones are scalemic natural products.

UR - http://www.scopus.com/inward/record.url?scp=85047518888&partnerID=8YFLogxK

U2 - 10.1071/CH18019

DO - 10.1071/CH18019

M3 - Article

SN - 0004-9425

VL - 71

SP - 366

EP - 372

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 5

ER -

Synthesis of Highly Enantio-Enriched Heliespirones A and C by a Diastereoselective Aromatic Claisen Rearrangement

Abstract

Access to Document

Other files and links

Fingerprint

Cite this