Synthesis of the enantiomer of the structure assigned to the natural product nobilisitine A

Brett D. Schwartz; Matthew T. Jones; Martin G. Banwell; Ian A. Cade

doi:10.1021/ol102249q

Synthesis of the enantiomer of the structure assigned to the natural product nobilisitine A

Brett D. Schwartz, Matthew T. Jones, Martin G. Banwell, Ian A. Cade

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

The synthesis of the enantiomer of the structure, 1, assigned to the natural product nobilisitine A has been accomplished using the enantiomerically pure cis-1,2-dihydrocatechol 4 as starting material. The ¹H and ¹³C NMR spectral data derived from compound ent-1 do not match those reported for the natural product, thus suggesting its structure has been incorrectly assigned.

Original language	English
Pages (from-to)	5210-5213
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	22
DOIs	https://doi.org/10.1021/ol102249q
Publication status	Published - 19 Nov 2010

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10.1021/ol102249q

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abstract = "The synthesis of the enantiomer of the structure, 1, assigned to the natural product nobilisitine A has been accomplished using the enantiomerically pure cis-1,2-dihydrocatechol 4 as starting material. The 1H and 13C NMR spectral data derived from compound ent-1 do not match those reported for the natural product, thus suggesting its structure has been incorrectly assigned.",

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AU - Cade, Ian A.

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AB - The synthesis of the enantiomer of the structure, 1, assigned to the natural product nobilisitine A has been accomplished using the enantiomerically pure cis-1,2-dihydrocatechol 4 as starting material. The 1H and 13C NMR spectral data derived from compound ent-1 do not match those reported for the natural product, thus suggesting its structure has been incorrectly assigned.

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Synthesis of the enantiomer of the structure assigned to the natural product nobilisitine A

Abstract

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