Synthons for carbide complex chemistry

Anders Reinholdt; Anthony F. Hill; Jesper Bendix

doi:10.1039/c8cc03596b

Synthons for carbide complex chemistry

Anders Reinholdt^*, Anthony F. Hill, Jesper Bendix

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The sterically accessible carbide complex, (Cy₃P)Cl₃RuC-PtCl(py)₂, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

Original language	English
Pages (from-to)	5708-5711
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	45
DOIs	https://doi.org/10.1039/c8cc03596b
Publication status	Published - 2018

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title = "Synthons for carbide complex chemistry",

abstract = "The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.",

author = "Anders Reinholdt and Hill, {Anthony F.} and Jesper Bendix",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

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T1 - Synthons for carbide complex chemistry

AU - Reinholdt, Anders

AU - Hill, Anthony F.

AU - Bendix, Jesper

PY - 2018

Y1 - 2018

N2 - The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

AB - The sterically accessible carbide complex, (Cy3P)Cl3RuC-PtCl(py)2, acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and A-frame scaffolds upon ligand addition. This concept, benefitting from coordination sphere selection as the concluding step, confronts traditional synthetic strategies and broadens the scope for carbide complexes.

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U2 - 10.1039/c8cc03596b

DO - 10.1039/c8cc03596b

M3 - Article

SN - 1359-7345

VL - 54

SP - 5708

EP - 5711

JO - Chemical Communications

JF - Chemical Communications

IS - 45

ER -

Synthons for carbide complex chemistry

Abstract

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