Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

Gerhard F. Swiegers; S. Bruce Wild

doi:10.1071/CH05253

Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

Gerhard F. Swiegers^*, S. Bruce Wild

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.

Original language	English
Pages (from-to)	831-833
Number of pages	3
Journal	Australian Journal of Chemistry
Volume	58
Issue number	12
DOIs	https://doi.org/10.1071/CH05253
Publication status	Published - 2005

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title = "Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)",

abstract = "The specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.",

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AU - Swiegers, Gerhard F.

AU - Wild, S. Bruce

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U2 - 10.1071/CH05253

DO - 10.1071/CH05253

M3 - Article

SN - 0004-9425

VL - 58

SP - 831

EP - 833

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 12

ER -

Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

Abstract

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