Templated rearrangement of silylated benzoxazolin-2-ones: A novel tridentate (ONO)2- chelating ligand system

Jörg Wagler; Anthony F. Hill

doi:10.1021/om700416b

Templated rearrangement of silylated benzoxazolin-2-ones: A novel tridentate (ONO)^2- chelating ligand system

Jörg Wagler^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.

Original language	English
Pages (from-to)	3630-3632
Number of pages	3
Journal	Organometallics
Volume	26
Issue number	15
DOIs	https://doi.org/10.1021/om700416b
Publication status	Published - 16 Jul 2007

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10.1021/om700416b

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title = "Templated rearrangement of silylated benzoxazolin-2-ones: A novel tridentate (ONO)2- chelating ligand system",

abstract = "The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.",

author = "J{\"o}rg Wagler and Hill, \{Anthony F.\}",

year = "2007",

month = jul,

day = "16",

doi = "10.1021/om700416b",

language = "English",

volume = "26",

pages = "3630--3632",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "15",

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TY - JOUR

T1 - Templated rearrangement of silylated benzoxazolin-2-ones

T2 - A novel tridentate (ONO)2- chelating ligand system

AU - Wagler, Jörg

AU - Hill, Anthony F.

PY - 2007/7/16

Y1 - 2007/7/16

N2 - The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.

AB - The reaction of phenyltrichlorosilane with benzoxazolin-2-one gives rise to phenyltris(benzoxazolin-2-on-l-yl)silane, which thermally rearranges to a pentacoordinate silicon compound bearing a novel (ONO) tridentate chelating ligand with interesting coordination properties.

UR - https://www.scopus.com/pages/publications/34547418116

U2 - 10.1021/om700416b

DO - 10.1021/om700416b

M3 - Article

SN - 0276-7333

VL - 26

SP - 3630

EP - 3632

JO - Organometallics

JF - Organometallics

IS - 15

ER -

Templated rearrangement of silylated benzoxazolin-2-ones: A novel tridentate (ONO)^2- chelating ligand system

Abstract

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