Templated synthesis and intact coordination of a diorganotriselenane: [RuCl2(PPh3){κ3-Se,N,N′-Se(mt Se)2}] (mtSe = selenomethimazolyl)

Rian D. Dewhurst; Andrew R. Hansen; Anthony F. Hill; Matthew K. Smith

doi:10.1021/om0608511

Templated synthesis and intact coordination of a diorganotriselenane: [RuCl₂(PPh₃){κ³-Se,N,N′-Se(mt ^Se)₂}] (mt^Se = selenomethimazolyl)

Rian D. Dewhurst, Andrew R. Hansen, Anthony F. Hill^*, Matthew K. Smith

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The reaction of [RuCl₂(PPh₃)₃] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ²-S,N-mt)₂(PPh₃) ₂], while the selenium analogue Hmt^Se provides an intact coordinated diorganotriselenane [Ru{κ³-Se,N,N′-Se(mt ^Se)₂}Ch(PPh₃)]. Bidentate mt^Se coordination is however observed in the complexes [RuR(κ²-Se,N) (CO)-(PPh₃)₂] (R = H, CH=CHC₆H ₄Me-4).

Original language	English
Pages (from-to)	5843-5846
Number of pages	4
Journal	Organometallics
Volume	25
Issue number	25
DOIs	https://doi.org/10.1021/om0608511
Publication status	Published - 4 Dec 2006

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title = "Templated synthesis and intact coordination of a diorganotriselenane: [RuCl2(PPh3){κ3-Se,N,N′-Se(mt Se)2}] (mtSe = selenomethimazolyl)",

abstract = "The reaction of [RuCl2(PPh3)3] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ2-S,N-mt)2(PPh3) 2], while the selenium analogue HmtSe provides an intact coordinated diorganotriselenane [Ru{κ3-Se,N,N′-Se(mt Se)2}Ch(PPh3)]. Bidentate mtSe coordination is however observed in the complexes [RuR(κ2-Se,N) (CO)-(PPh3)2] (R = H, CH=CHC6H 4Me-4).",

author = "Dewhurst, {Rian D.} and Hansen, {Andrew R.} and Hill, {Anthony F.} and Smith, {Matthew K.}",

year = "2006",

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T1 - Templated synthesis and intact coordination of a diorganotriselenane

T2 - [RuCl2(PPh3){κ3-Se,N,N′-Se(mt Se)2}] (mtSe = selenomethimazolyl)

AU - Dewhurst, Rian D.

AU - Hansen, Andrew R.

AU - Hill, Anthony F.

AU - Smith, Matthew K.

PY - 2006/12/4

Y1 - 2006/12/4

N2 - The reaction of [RuCl2(PPh3)3] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ2-S,N-mt)2(PPh3) 2], while the selenium analogue HmtSe provides an intact coordinated diorganotriselenane [Ru{κ3-Se,N,N′-Se(mt Se)2}Ch(PPh3)]. Bidentate mtSe coordination is however observed in the complexes [RuR(κ2-Se,N) (CO)-(PPh3)2] (R = H, CH=CHC6H 4Me-4).

AB - The reaction of [RuCl2(PPh3)3] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ2-S,N-mt)2(PPh3) 2], while the selenium analogue HmtSe provides an intact coordinated diorganotriselenane [Ru{κ3-Se,N,N′-Se(mt Se)2}Ch(PPh3)]. Bidentate mtSe coordination is however observed in the complexes [RuR(κ2-Se,N) (CO)-(PPh3)2] (R = H, CH=CHC6H 4Me-4).

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U2 - 10.1021/om0608511

DO - 10.1021/om0608511

M3 - Article

SN - 0276-7333

VL - 25

SP - 5843

EP - 5846

JO - Organometallics

JF - Organometallics

IS - 25

ER -

Templated synthesis and intact coordination of a diorganotriselenane: [RuCl₂(PPh₃){κ³-Se,N,N′-Se(mt ^Se)₂}] (mt^Se = selenomethimazolyl)

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