Abstract
The reaction of [W(CCCSiMe3)(CO)2(Tp∗)] (Tp∗ = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W(CCCAg)-(CO)2(Tp∗)][AgNO3]}n while [Hg{CCCW(CO)2(Tp∗)}2] with nBuLi affords [W(CCCLi)(CO)2(Tp∗)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.
Original language | English |
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Pages (from-to) | 14597-14600 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 56 |
Issue number | 93 |
DOIs | |
Publication status | Published - 4 Dec 2020 |