Tetrel and pnictogen functionalised propargylidynes

Richard A. Manzano; Anthony F. Hill; Rosemary L. Georgelin

doi:10.1039/d0cc06196d

Tetrel and pnictogen functionalised propargylidynes

Richard A. Manzano, Anthony F. Hill, Rosemary L. Georgelin

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of [W(CCCSiMe3)(CO)2(Tp∗)] (Tp∗ = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W(CCCAg)-(CO)2(Tp∗)][AgNO3]}n while [Hg{CCCW(CO)2(Tp∗)}2] with nBuLi affords [W(CCCLi)(CO)2(Tp∗)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.

Original language	English
Pages (from-to)	14597-14600
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	93
DOIs	https://doi.org/10.1039/d0cc06196d
Publication status	Published - 4 Dec 2020

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title = "Tetrel and pnictogen functionalised propargylidynes",

abstract = "The reaction of [W(CCCSiMe3)(CO)2(Tp∗)] (Tp∗ = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W(CCCAg)-(CO)2(Tp∗)][AgNO3]}n while [Hg{CCCW(CO)2(Tp∗)}2] with nBuLi affords [W(CCCLi)(CO)2(Tp∗)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.",

author = "Manzano, {Richard A.} and Hill, {Anthony F.} and Georgelin, {Rosemary L.}",

note = "Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

year = "2020",

month = dec,

day = "4",

doi = "10.1039/d0cc06196d",

language = "English",

volume = "56",

pages = "14597--14600",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Tetrel and pnictogen functionalised propargylidynes

AU - Manzano, Richard A.

AU - Hill, Anthony F.

AU - Georgelin, Rosemary L.

PY - 2020/12/4

Y1 - 2020/12/4

N2 - The reaction of [W(CCCSiMe3)(CO)2(Tp∗)] (Tp∗ = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W(CCCAg)-(CO)2(Tp∗)][AgNO3]}n while [Hg{CCCW(CO)2(Tp∗)}2] with nBuLi affords [W(CCCLi)(CO)2(Tp∗)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.

AB - The reaction of [W(CCCSiMe3)(CO)2(Tp∗)] (Tp∗ = tris(dimethylpyrazolyl)borate) with AgNO3 affords {[W(CCCAg)-(CO)2(Tp∗)][AgNO3]}n while [Hg{CCCW(CO)2(Tp∗)}2] with nBuLi affords [W(CCCLi)(CO)2(Tp∗)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.

UR - http://www.scopus.com/inward/record.url?scp=85096859686&partnerID=8YFLogxK

U2 - 10.1039/d0cc06196d

DO - 10.1039/d0cc06196d

M3 - Article

SN - 1359-7345

VL - 56

SP - 14597

EP - 14600

JO - Chemical Communications

JF - Chemical Communications

IS - 93

ER -

Tetrel and pnictogen functionalised propargylidynes

Abstract

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