The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages

Logan A.V. Faulkner; James D. Crowley

doi:10.1016/j.chempr.2024.01.015

The beauty of low symmetry: Non-statistical assembly of [Pd₂(L_A)(L_B)(L_C)(L_D)]⁴⁺ cages

Logan A.V. Faulkner, James D. Crowley^*

^*Corresponding author for this work

Research output: Contribution to journal › Comment/debate › peer-review

3 Citations (Scopus)

Abstract

Clever and co-workers have developed an elegant method for the quantitative synthesis of a low-symmetry heteroleptic [Pd₂(L_A)(L_B)(L_C)(L_D)]⁴⁺ cage. The cage is formed under thermodynamic control and can be accessed through multiple different pathways. Compared with their high-symmetry siblings, these types of low-symmetry cages should display enhanced molecular-recognition properties (selectivity).

Original language	English
Pages (from-to)	440-442
Number of pages	3
Journal	Chem
Volume	10
Issue number	2
Early online date	31 Jan 2024
DOIs	https://doi.org/10.1016/j.chempr.2024.01.015
Publication status	Published - 8 Feb 2024
Externally published	Yes

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10.1016/j.chempr.2024.01.015

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title = "The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages",

abstract = "Clever and co-workers have developed an elegant method for the quantitative synthesis of a low-symmetry heteroleptic [Pd2(LA)(LB)(LC)(LD)]4+ cage. The cage is formed under thermodynamic control and can be accessed through multiple different pathways. Compared with their high-symmetry siblings, these types of low-symmetry cages should display enhanced molecular-recognition properties (selectivity).",

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AU - Crowley, James D.

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N2 - Clever and co-workers have developed an elegant method for the quantitative synthesis of a low-symmetry heteroleptic [Pd2(LA)(LB)(LC)(LD)]4+ cage. The cage is formed under thermodynamic control and can be accessed through multiple different pathways. Compared with their high-symmetry siblings, these types of low-symmetry cages should display enhanced molecular-recognition properties (selectivity).

AB - Clever and co-workers have developed an elegant method for the quantitative synthesis of a low-symmetry heteroleptic [Pd2(LA)(LB)(LC)(LD)]4+ cage. The cage is formed under thermodynamic control and can be accessed through multiple different pathways. Compared with their high-symmetry siblings, these types of low-symmetry cages should display enhanced molecular-recognition properties (selectivity).

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The beauty of low symmetry: Non-statistical assembly of [Pd₂(L_A)(L_B)(L_C)(L_D)]⁴⁺ cages

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