The coordination chemistry of 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Complexes of ruthenium, osmium and iridium

Max Herberhold; Anthony F. Hill

doi:10.1016/0022-328X(89)80061-0

The coordination chemistry of 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Complexes of ruthenium, osmium and iridium

Max Herberhold^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The reactions of [MCl(C₆H₄Me-4)(CO)(PPh₃)₂] (M Ru, Os) and [IrCl₂H(PPh₃)₃] with 2,1,3-benzothiadiazole (BTD) result in quantitative formation of the adducts [MCl(C₆H₄Me-4)(CO)(PPh₃)₂(BTD)] and [IrCl₂H(PPh₃)₂(BTD)], respectively. Similar reactions with 2,1,3-benzoselenadiazole (BSD) provide the corresponding selenium analogues. The thiocarbonyl complex [OsCl₂(CS)(PPh₃)₂-(BSD)] is obtained by replacement of one phosphine in [OsCl₂(CS)(PPh₃)₃]. The BSD and BTD ligands in the complexes are labile; [OsCl(C₆H₄Me-4)(CO)(PPh₃)₂-(BSD)] reacts with carbon monoxide and N,N-dimethylthionitrosamine to give [OsCl(C₆H₄Me-4)(CO)₂(PPh₃)₂] and [OsCl(C₆H₄Me-4)(CO)(PPh₃)₂(SNNMe₂)], respectively. The IR, ¹H, and ³¹P-{¹H} NMR data for the new complexes are reported and discussed.

Original language	English
Pages (from-to)	151-156
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	377
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(89)80061-0
Publication status	Published - 14 Nov 1989
Externally published	Yes

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@article{6c457e39f137424eb45f5d50c96c4cee,

title = "The coordination chemistry of 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Complexes of ruthenium, osmium and iridium",

abstract = "The reactions of [MCl(C6H4Me-4)(CO)(PPh3)2] (M Ru, Os) and [IrCl2H(PPh3)3] with 2,1,3-benzothiadiazole (BTD) result in quantitative formation of the adducts [MCl(C6H4Me-4)(CO)(PPh3)2(BTD)] and [IrCl2H(PPh3)2(BTD)], respectively. Similar reactions with 2,1,3-benzoselenadiazole (BSD) provide the corresponding selenium analogues. The thiocarbonyl complex [OsCl2(CS)(PPh3)2-(BSD)] is obtained by replacement of one phosphine in [OsCl2(CS)(PPh3)3]. The BSD and BTD ligands in the complexes are labile; [OsCl(C6H4Me-4)(CO)(PPh3)2-(BSD)] reacts with carbon monoxide and N,N-dimethylthionitrosamine to give [OsCl(C6H4Me-4)(CO)2(PPh3)2] and [OsCl(C6H4Me-4)(CO)(PPh3)2(SNNMe2)], respectively. The IR, 1H, and 31P-{1H} NMR data for the new complexes are reported and discussed.",

author = "Max Herberhold and Hill, {Anthony F.}",

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doi = "10.1016/0022-328X(89)80061-0",

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T1 - The coordination chemistry of 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Complexes of ruthenium, osmium and iridium

AU - Herberhold, Max

AU - Hill, Anthony F.

PY - 1989/11/14

Y1 - 1989/11/14

N2 - The reactions of [MCl(C6H4Me-4)(CO)(PPh3)2] (M Ru, Os) and [IrCl2H(PPh3)3] with 2,1,3-benzothiadiazole (BTD) result in quantitative formation of the adducts [MCl(C6H4Me-4)(CO)(PPh3)2(BTD)] and [IrCl2H(PPh3)2(BTD)], respectively. Similar reactions with 2,1,3-benzoselenadiazole (BSD) provide the corresponding selenium analogues. The thiocarbonyl complex [OsCl2(CS)(PPh3)2-(BSD)] is obtained by replacement of one phosphine in [OsCl2(CS)(PPh3)3]. The BSD and BTD ligands in the complexes are labile; [OsCl(C6H4Me-4)(CO)(PPh3)2-(BSD)] reacts with carbon monoxide and N,N-dimethylthionitrosamine to give [OsCl(C6H4Me-4)(CO)2(PPh3)2] and [OsCl(C6H4Me-4)(CO)(PPh3)2(SNNMe2)], respectively. The IR, 1H, and 31P-{1H} NMR data for the new complexes are reported and discussed.

AB - The reactions of [MCl(C6H4Me-4)(CO)(PPh3)2] (M Ru, Os) and [IrCl2H(PPh3)3] with 2,1,3-benzothiadiazole (BTD) result in quantitative formation of the adducts [MCl(C6H4Me-4)(CO)(PPh3)2(BTD)] and [IrCl2H(PPh3)2(BTD)], respectively. Similar reactions with 2,1,3-benzoselenadiazole (BSD) provide the corresponding selenium analogues. The thiocarbonyl complex [OsCl2(CS)(PPh3)2-(BSD)] is obtained by replacement of one phosphine in [OsCl2(CS)(PPh3)3]. The BSD and BTD ligands in the complexes are labile; [OsCl(C6H4Me-4)(CO)(PPh3)2-(BSD)] reacts with carbon monoxide and N,N-dimethylthionitrosamine to give [OsCl(C6H4Me-4)(CO)2(PPh3)2] and [OsCl(C6H4Me-4)(CO)(PPh3)2(SNNMe2)], respectively. The IR, 1H, and 31P-{1H} NMR data for the new complexes are reported and discussed.

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U2 - 10.1016/0022-328X(89)80061-0

DO - 10.1016/0022-328X(89)80061-0

M3 - Article

AN - SCOPUS:0043212454

SN - 0022-328X

VL - 377

SP - 151

EP - 156

JO - Journal of Organometallic Chemistry

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ER -

The coordination chemistry of 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole. Complexes of ruthenium, osmium and iridium

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