TY - JOUR
T1 - The coordination chemistry of iminooxosulphuranes. III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)
AU - Herberhold, Max
AU - Hill, Anthony F.
PY - 1989/5/23
Y1 - 1989/5/23
N2 - The tris(phosphine) complexes [Ru(CO)(PPh3)3(L)] (L = CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes. RNSO, (R = C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh3)2(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh3)2(L)(SO2)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.
AB - The tris(phosphine) complexes [Ru(CO)(PPh3)3(L)] (L = CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes. RNSO, (R = C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh3)2(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh3)2(L)(SO2)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.
UR - http://www.scopus.com/inward/record.url?scp=0004918019&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(89)80123-8
DO - 10.1016/0022-328X(89)80123-8
M3 - Article
AN - SCOPUS:0004918019
SN - 0022-328X
VL - 368
SP - 111
EP - 117
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -