TY - JOUR
T1 - The coordination chemistry of iminooxosulphuranes. IV. The reactions of [WH(CO)3(η-C5H5)] with iminooxosulphuranes and diiminosulphuranes
AU - Ehrenreich, Wolfgang P.
AU - Herberhold, Max
AU - Hill, Anthony F.
PY - 1989/8/1
Y1 - 1989/8/1
N2 - The tungsten hydride [WH(CO)3(η-C5H5)] reacts with iminooxosulphuranes, RNSO (R = C6H4Me-2, C6H4Me-4), to give the tungsten sulphinamides [W{S(O)NHR}(CO)3(η-C5H5]. Diiminosulphuranes bearing electron-withdrawing substituents, R′NSNSO2C6H4Me-4 (R′ = C6H5, SO2C6H4Me-4), insert into the metalhydrogen bond of [WH(CO)3(η-C5H5)] to give [W{S(NR)NHSO2C6H4-Me-4}(CO)3(η-C5H5)], whilst bis(p-tolylimino)sulphurane, S(NC6H4Me-4)2, gives the tungstacycle [W{S(NHC6H4Me-4)N(C6H4ME-4)C(0)}(CO)2(η-C5H5)]. A comprehensive mechanism is discussed.
AB - The tungsten hydride [WH(CO)3(η-C5H5)] reacts with iminooxosulphuranes, RNSO (R = C6H4Me-2, C6H4Me-4), to give the tungsten sulphinamides [W{S(O)NHR}(CO)3(η-C5H5]. Diiminosulphuranes bearing electron-withdrawing substituents, R′NSNSO2C6H4Me-4 (R′ = C6H5, SO2C6H4Me-4), insert into the metalhydrogen bond of [WH(CO)3(η-C5H5)] to give [W{S(NR)NHSO2C6H4-Me-4}(CO)3(η-C5H5)], whilst bis(p-tolylimino)sulphurane, S(NC6H4Me-4)2, gives the tungstacycle [W{S(NHC6H4Me-4)N(C6H4ME-4)C(0)}(CO)2(η-C5H5)]. A comprehensive mechanism is discussed.
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UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1989AJ57600004&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1016/0022-328X(89)85226-X
DO - 10.1016/0022-328X(89)85226-X
M3 - Article
AN - SCOPUS:45249128600
SN - 0022-328X
VL - 371
SP - 303
EP - 310
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -