The coordination chemistry of iminooxosulphuranes. V. The osmium and iridium series [MLCl(PPh3)2(OSA)] (ML = OsNo, IrCO; A = O, CH2, S, NR; R = o-tolyl, p-tolyl and p-tosyl)

Max Herberhold; Anthony F. Hill

doi:10.1016/0022-328X(90)87181-C

The coordination chemistry of iminooxosulphuranes. V. The osmium and iridium series [MLCl(PPh₃)₂(OSA)] (ML = OsNo, IrCO; A = O, CH₂, S, NR; R = o-tolyl, p-tolyl and p-tosyl)

Max Herberhold^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The preparation and characterisation of the two analogous series of compounds [OsCl(NO)(PPh₃)₂(OSA)] (A = O, CH₂, S, NR; R = C₆H₄Me-4, C₆H₄Me-2, SO₂C₆H₄Me-4) and [IrCl(CO)(PPh₃)₂(OSA)] (A = O, S, NSO₂C₆H₄Me-4) are described. A comparison of spectroscopic data for the complexes supports the isolobal relationship between the molecules OSA.

Original language	English
Pages (from-to)	323-336
Number of pages	14
Journal	Journal of Organometallic Chemistry
Volume	387
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(90)87181-C
Publication status	Published - 8 May 1990
Externally published	Yes

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title = "The coordination chemistry of iminooxosulphuranes. V. The osmium and iridium series [MLCl(PPh3)2(OSA)] (ML = OsNo, IrCO; A = O, CH2, S, NR; R = o-tolyl, p-tolyl and p-tosyl)",

abstract = "The preparation and characterisation of the two analogous series of compounds [OsCl(NO)(PPh3)2(OSA)] (A = O, CH2, S, NR; R = C6H4Me-4, C6H4Me-2, SO2C6H4Me-4) and [IrCl(CO)(PPh3)2(OSA)] (A = O, S, NSO2C6H4Me-4) are described. A comparison of spectroscopic data for the complexes supports the isolobal relationship between the molecules OSA.",

author = "Max Herberhold and Hill, {Anthony F.}",

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doi = "10.1016/0022-328X(90)87181-C",

language = "English",

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T1 - The coordination chemistry of iminooxosulphuranes. V. The osmium and iridium series [MLCl(PPh3)2(OSA)] (ML = OsNo, IrCO; A = O, CH2, S, NR; R = o-tolyl, p-tolyl and p-tosyl)

AU - Herberhold, Max

AU - Hill, Anthony F.

PY - 1990/5/8

Y1 - 1990/5/8

N2 - The preparation and characterisation of the two analogous series of compounds [OsCl(NO)(PPh3)2(OSA)] (A = O, CH2, S, NR; R = C6H4Me-4, C6H4Me-2, SO2C6H4Me-4) and [IrCl(CO)(PPh3)2(OSA)] (A = O, S, NSO2C6H4Me-4) are described. A comparison of spectroscopic data for the complexes supports the isolobal relationship between the molecules OSA.

AB - The preparation and characterisation of the two analogous series of compounds [OsCl(NO)(PPh3)2(OSA)] (A = O, CH2, S, NR; R = C6H4Me-4, C6H4Me-2, SO2C6H4Me-4) and [IrCl(CO)(PPh3)2(OSA)] (A = O, S, NSO2C6H4Me-4) are described. A comparison of spectroscopic data for the complexes supports the isolobal relationship between the molecules OSA.

UR - http://www.scopus.com/inward/record.url?scp=0000880174&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(90)87181-C

DO - 10.1016/0022-328X(90)87181-C

M3 - Article

AN - SCOPUS:0000880174

SN - 0022-328X

VL - 387

SP - 323

EP - 336

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

The coordination chemistry of iminooxosulphuranes. V. The osmium and iridium series [MLCl(PPh₃)₂(OSA)] (ML = OsNo, IrCO; A = O, CH₂, S, NR; R = o-tolyl, p-tolyl and p-tosyl)

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