The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)

Max Herberhold; Anthony F. Hill

doi:10.1016/0022-328X(89)80123-8

The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)

Max Herberhold^*, Anthony F. Hill

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The tris(phosphine) complexes [Ru(CO)(PPh₃)₃(L)] (L = CO, CN^tBu, CNC₆H₃Me₂-2,6) react with iminooxosulphuranes. RNSO, (R = C₆H₄Me-2, C₆H₄Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh₃)₂(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh₃)₂(L)(SO₂)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.

Original language	English
Pages (from-to)	111-117
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	368
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(89)80123-8
Publication status	Published - 23 May 1989
Externally published	Yes

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title = "The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)",

abstract = "The tris(phosphine) complexes [Ru(CO)(PPh3)3(L)] (L = CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes. RNSO, (R = C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh3)2(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh3)2(L)(SO2)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.",

author = "Max Herberhold and Hill, \{Anthony F.\}",

year = "1989",

month = may,

day = "23",

doi = "10.1016/0022-328X(89)80123-8",

language = "English",

volume = "368",

pages = "111--117",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1",

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TY - JOUR

T1 - The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)

AU - Herberhold, Max

AU - Hill, Anthony F.

PY - 1989/5/23

Y1 - 1989/5/23

N2 - The tris(phosphine) complexes [Ru(CO)(PPh3)3(L)] (L = CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes. RNSO, (R = C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh3)2(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh3)2(L)(SO2)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.

AB - The tris(phosphine) complexes [Ru(CO)(PPh3)3(L)] (L = CO, CNtBu, CNC6H3Me2-2,6) react with iminooxosulphuranes. RNSO, (R = C6H4Me-2, C6H4Me-4) by a displacement of one labile phosphine ligand to provide [Ru(CO)(PPh3)2(L)(OSNR)]. Spectroscopic data indicate that the heterocumulenes are bound to ruthenium through both nitrogen and sulphur. Sulphur dioxide coordinates in a similar bidentate mode, through sulphur and oxygen, in the complexes [Ru(CO)(PPh3)2(L)(SO2)] that are obtained upon treatment of the corresponding tris(phosphine) precursors with gaseous sulphur dioxide.

UR - https://www.scopus.com/pages/publications/0004918019

U2 - 10.1016/0022-328X(89)80123-8

DO - 10.1016/0022-328X(89)80123-8

M3 - Article

AN - SCOPUS:0004918019

SN - 0022-328X

VL - 368

SP - 111

EP - 117

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

The coordination chemistry of iminooxosulphuranes: III. Synthesis of the ruthenium complexes [Ru(OC)(PPh3)2(L)(OSNR)] (L = CO, CNtBu, CNC6H3Me2-2,6; R = C6H4Me-2, C6H4Me-4)

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