The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]

Anthony F. Hill; George R. Clark; Clifton E.F. Rickard; Warren R. Roper; Max Herberhold

doi:10.1016/0022-328X(91)86232-F

The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]

Anthony F. Hill
, George R. Clark
, Clifton E.F. Rickard
, Warren R. Roper
, Max Herberhold

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4) has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (η²-NS), with the pyramidal sulphur trans to chloride.

Original language	English
Pages (from-to)	357-362
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	401
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(91)86232-F
Publication status	Published - 15 Jan 1991
Externally published	Yes

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10.1016/0022-328X(91)86232-F

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title = "The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]",

abstract = "The crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4) has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (η2-NS), with the pyramidal sulphur trans to chloride.",

keywords = "Double-bond systems, Molecular-structure, N-sulfinylaniline, Complexes, Ligands",

author = "Hill, \{Anthony F.\} and Clark, \{George R.\} and Rickard, \{Clifton E.F.\} and Roper, \{Warren R.\} and Max Herberhold",

year = "1991",

month = jan,

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doi = "10.1016/0022-328X(91)86232-F",

language = "English",

volume = "401",

pages = "357--362",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

}

The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]. / Hill, Anthony F.; Clark, George R.; Rickard, Clifton E.F. et al.
In: Journal of Organometallic Chemistry, Vol. 401, No. 3, 15.01.1991, p. 357-362.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]

AU - Hill, Anthony F.

AU - Clark, George R.

AU - Rickard, Clifton E.F.

AU - Roper, Warren R.

AU - Herberhold, Max

PY - 1991/1/15

Y1 - 1991/1/15

N2 - The crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4) has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (η2-NS), with the pyramidal sulphur trans to chloride.

AB - The crystal structure of the complex trans-[OsCl(NO)(PPh3)2(OSNC6H4Me-4) has been determined and confirms that the sulphur(IV) heterocumulene adopts a pseudo-olefinic mode of coordination (η2-NS), with the pyramidal sulphur trans to chloride.

KW - Double-bond systems

KW - Molecular-structure

KW - N-sulfinylaniline

KW - Complexes

KW - Ligands

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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The coordination chemistry of iminooxosulphuranes: X. Pseudo-olefinic coordination of OSNC6H4Me-4 to zerovalent osmium. Crystal structure of [OsCl(NO)(PPh3)2(OSNC6H4Me-4)]

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