The coupling of methylene and vinyl ligands at a ruthenium(II) centre

Anthony F. Hill; Chean T. Ho; James D.E.T. Wilton-Ely

doi:10.1039/a704157h

The coupling of methylene and vinyl ligands at a ruthenium(II) centre

Anthony F. Hill^*, Chean T. Ho, James D.E.T. Wilton-Ely

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

67 Citations (Scopus)

Abstract

The reaction of [Ru(CH=CH₂)Cl(CO)(PPh₃)₂] with diazomethane provides the allyl complex [Ru(η³-CH₂CHCH₂)Cl(CO)(PPh ₃)₂] which is also the product of the reactions of [RuHCl(CO)(PPh₃)₃] with either allene or propyne and which reacts subsequently with NaS₂CNMe₂ to provide [RuH(S₂CNMe₂)(CO)(PPh₃)₂] and allene.

Original language	English
Pages (from-to)	2207-2208
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/a704157h
Publication status	Published - 1997
Externally published	Yes

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title = "The coupling of methylene and vinyl ligands at a ruthenium(II) centre",

abstract = "The reaction of [Ru(CH=CH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh 3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.",

author = "Hill, {Anthony F.} and Ho, {Chean T.} and Wilton-Ely, {James D.E.T.}",

year = "1997",

doi = "10.1039/a704157h",

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pages = "2207--2208",

journal = "Chemical Communications",

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T1 - The coupling of methylene and vinyl ligands at a ruthenium(II) centre

AU - Hill, Anthony F.

AU - Ho, Chean T.

AU - Wilton-Ely, James D.E.T.

PY - 1997

Y1 - 1997

N2 - The reaction of [Ru(CH=CH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh 3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.

AB - The reaction of [Ru(CH=CH2)Cl(CO)(PPh3)2] with diazomethane provides the allyl complex [Ru(η3-CH2CHCH2)Cl(CO)(PPh 3)2] which is also the product of the reactions of [RuHCl(CO)(PPh3)3] with either allene or propyne and which reacts subsequently with NaS2CNMe2 to provide [RuH(S2CNMe2)(CO)(PPh3)2] and allene.

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U2 - 10.1039/a704157h

DO - 10.1039/a704157h

M3 - Article

AN - SCOPUS:0002082577

SN - 1359-7345

SP - 2207

EP - 2208

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

The coupling of methylene and vinyl ligands at a ruthenium(II) centre

Abstract

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