The d1Πg(v=1) Rydberg state of O2: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b1Σg+(v=0)-state platform

P. O'Keeffe*, T. Ridley, H. A. Sheard, K. P. Lawley, R. J. Donovan, B. R. Lewis

*Corresponding author for this work

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    Abstract

    The d←←b(1,0) band of O2 following Huggins-band photolysis of O3 was explored. Analyses of these REMPI spectra yield, not only the first information on d(v=1) rotational levels with J>29, but also the first estimate of an O2(b-state fragment rotational distribution in O3) photolysis. These data were supported by an OODR-REMPI study of the J=1-18 levels of d(v=1).

    Original languageEnglish
    Pages (from-to)8705-8709
    Number of pages5
    JournalJournal of Chemical Physics
    Volume117
    Issue number19
    DOIs
    Publication statusPublished - 15 Nov 2002

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