The d1Πg(v=1) Rydberg state of O2: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b1Σg+(v=0)-state platform

P. O'Keeffe; T. Ridley; H. A. Sheard; K. P. Lawley; R. J. Donovan; B. R. Lewis

doi:10.1063/1.1513462

The d¹Π_g(v=1) Rydberg state of O₂: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b¹Σ_g⁺(v=0)-state platform

P. O'Keeffe^*, T. Ridley, H. A. Sheard, K. P. Lawley, R. J. Donovan, B. R. Lewis

^*Corresponding author for this work

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6 Citations (Scopus)

Abstract

The d←←b(1,0) band of O₂ following Huggins-band photolysis of O₃ was explored. Analyses of these REMPI spectra yield, not only the first information on d(v=1) rotational levels with J>29, but also the first estimate of an O₂(b-state fragment rotational distribution in O₃) photolysis. These data were supported by an OODR-REMPI study of the J=1-18 levels of d(v=1).

Original language	English
Pages (from-to)	8705-8709
Number of pages	5
Journal	Journal of Chemical Physics
Volume	117
Issue number	19
DOIs	https://doi.org/10.1063/1.1513462
Publication status	Published - 15 Nov 2002

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@article{5c6b67f8095d4dd9b50b6e48b3c8a897,

title = "The d1Πg(v=1) Rydberg state of O2: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b1Σg+(v=0)-state platform",

abstract = "The d←←b(1,0) band of O2 following Huggins-band photolysis of O3 was explored. Analyses of these REMPI spectra yield, not only the first information on d(v=1) rotational levels with J>29, but also the first estimate of an O2(b-state fragment rotational distribution in O3) photolysis. These data were supported by an OODR-REMPI study of the J=1-18 levels of d(v=1).",

author = "P. O'Keeffe and T. Ridley and Sheard, \{H. A.\} and Lawley, \{K. P.\} and Donovan, \{R. J.\} and Lewis, \{B. R.\}",

year = "2002",

month = nov,

day = "15",

doi = "10.1063/1.1513462",

language = "English",

volume = "117",

pages = "8705--8709",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "19",

}

The d¹Π_g(v=1) Rydberg state of O₂: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b¹Σ_g⁺(v=0)-state platform. / O'Keeffe, P.; Ridley, T.; Sheard, H. A. et al.
In: Journal of Chemical Physics, Vol. 117, No. 19, 15.11.2002, p. 8705-8709.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The d1Πg(v=1) Rydberg state of O2

T2 - Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b1Σg+(v=0)-state platform

AU - O'Keeffe, P.

AU - Ridley, T.

AU - Sheard, H. A.

AU - Lawley, K. P.

AU - Donovan, R. J.

AU - Lewis, B. R.

PY - 2002/11/15

Y1 - 2002/11/15

N2 - The d←←b(1,0) band of O2 following Huggins-band photolysis of O3 was explored. Analyses of these REMPI spectra yield, not only the first information on d(v=1) rotational levels with J>29, but also the first estimate of an O2(b-state fragment rotational distribution in O3) photolysis. These data were supported by an OODR-REMPI study of the J=1-18 levels of d(v=1).

AB - The d←←b(1,0) band of O2 following Huggins-band photolysis of O3 was explored. Analyses of these REMPI spectra yield, not only the first information on d(v=1) rotational levels with J>29, but also the first estimate of an O2(b-state fragment rotational distribution in O3) photolysis. These data were supported by an OODR-REMPI study of the J=1-18 levels of d(v=1).

UR - https://www.scopus.com/pages/publications/0037113159

U2 - 10.1063/1.1513462

DO - 10.1063/1.1513462

M3 - Article

SN - 0021-9606

VL - 117

SP - 8705

EP - 8709

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 19

ER -

The d¹Π_g(v=1) Rydberg state of O₂: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b¹Σ_g⁺(v=0)-state platform

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