The effect of V/III ratio and catalyst particle size on the crystal structure and optical properties of InP nanowires

S. Paiman*, Q. Gao, H. H. Tan, C. Jagadish, K. Pemasiri, M. Montazeri, H. E. Jackson, L. M. Smith, J. M. Yarrison-Rice, X. Zhang, J. Zou

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    102 Citations (Scopus)

    Abstract

    InP nanowires were grown on (111)B InP substrates by metal-organic chemical vapour deposition in the presence of colloidal gold particles as catalysts. Transmission electron microscopy and photoluminescence measurements were carried out to investigate the effects of V/III ratio and nanowire diameter on structural and optical properties. Results show that InP nanowires grow preferably in the wurtzite crystal structure than the zinc blende crystal structure with increasing V/III ratio or decreasing diameter. Additionally, time-resolved photoluminescence (TRPL) studies have revealed that wurtzite nanowires show longer recombination lifetimes of ∼2500ps with notably higher quantum efficiencies.

    Original languageEnglish
    Article number225606
    JournalNanotechnology
    Volume20
    Issue number22
    DOIs
    Publication statusPublished - 2009

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