The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

Xiangting Zhou; Anthony I. Day; Anthony C. Willis; W. Gregory Jackson

doi:10.1039/b305182j

The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

Xiangting Zhou, Anthony I. Day, Anthony C. Willis, W. Gregory Jackson^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH₂)]²⁺ and sym-syn-[Co(L-C)(OH₂)]²⁺ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO₄ remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.

Original language	English
Pages (from-to)	2386-2387
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	18
DOIs	https://doi.org/10.1039/b305182j
Publication status	Published - 2003

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title = "The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane",

abstract = "Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)]2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.",

author = "Xiangting Zhou and Day, {Anthony I.} and Willis, {Anthony C.} and Jackson, {W. Gregory}",

year = "2003",

doi = "10.1039/b305182j",

language = "English",

volume = "3",

pages = "2386--2387",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

AU - Zhou, Xiangting

AU - Day, Anthony I.

AU - Willis, Anthony C.

AU - Jackson, W. Gregory

PY - 2003

Y1 - 2003

N2 - Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)]2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.

AB - Two isomeric C-bonded complexes, sym-anti-[Co(L-C)(OH2)]2+ and sym-syn-[Co(L-C)(OH2)]2+ (L = 1,4,8,11-tetraazabicyclo[9.5.2]octadecane) when crystallised from aqueous NaClO4 remarkably yielded the corresponding perchlorato complexes, confirmed by the single crystal X-ray structures.

UR - http://www.scopus.com/inward/record.url?scp=0141455909&partnerID=8YFLogxK

U2 - 10.1039/b305182j

DO - 10.1039/b305182j

M3 - Article

SN - 1359-7345

VL - 3

SP - 2386

EP - 2387

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

The first structurally characterised perchlorato-cobalt(iii) complexes, involving the C-bonded macrobicyclic ligand 1,4,8,11-tetraazabicyclo[9.5.2]octadecane

Abstract

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