The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors

Martin G. Banwell; Daniel A.S. Beck; Jason A. Smith

doi:10.1039/b312552a

The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors

Martin G. Banwell^*, Daniel A.S. Beck, Jason A. Smith

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

76 Citations (Scopus)

Abstract

A series of pyrroles incorporating N-tethered acrylates and related groups has been prepared and examined for their capacity to undergo intramolecular Michael addition reactions to form, in a diastereo- or enantio-selective fashion, the corresponding 8-substituted tetrahydroindolizidine or homologues thereof.

Original language	English
Pages (from-to)	157-159
Number of pages	3
Journal	Organic and Biomolecular Chemistry
Volume	2
Issue number	2
DOIs	https://doi.org/10.1039/b312552a
Publication status	Published - 21 Jan 2004

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title = "The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors",

abstract = "A series of pyrroles incorporating N-tethered acrylates and related groups has been prepared and examined for their capacity to undergo intramolecular Michael addition reactions to form, in a diastereo- or enantio-selective fashion, the corresponding 8-substituted tetrahydroindolizidine or homologues thereof.",

author = "Banwell, {Martin G.} and Beck, {Daniel A.S.} and Smith, {Jason A.}",

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AU - Banwell, Martin G.

AU - Beck, Daniel A.S.

AU - Smith, Jason A.

PY - 2004/1/21

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N2 - A series of pyrroles incorporating N-tethered acrylates and related groups has been prepared and examined for their capacity to undergo intramolecular Michael addition reactions to form, in a diastereo- or enantio-selective fashion, the corresponding 8-substituted tetrahydroindolizidine or homologues thereof.

AB - A series of pyrroles incorporating N-tethered acrylates and related groups has been prepared and examined for their capacity to undergo intramolecular Michael addition reactions to form, in a diastereo- or enantio-selective fashion, the corresponding 8-substituted tetrahydroindolizidine or homologues thereof.

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U2 - 10.1039/b312552a

DO - 10.1039/b312552a

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EP - 159

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 2

ER -

The influence of chiral auxiliaries and catalysts on the selectivity of intramolecular conjugate additions of pyrrole to N-tethered Michael acceptors

Abstract

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