The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C 6Li and C 12Li

Mark J. Henderson; Takatoshi Nishimura; John W. White

doi:10.1021/ic300269n

The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C ₆Li and C ₁₂Li

Mark J. Henderson, Takatoshi Nishimura, John W. White^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C ₆Li or C ₁₂Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The ¹³C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.

Original language	English
Pages (from-to)	4426-4428
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	8
DOIs	https://doi.org/10.1021/ic300269n
Publication status	Published - 16 Apr 2012

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title = "The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C 6Li and C 12Li",

abstract = "Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C 6Li or C 12Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 {\AA}. The 13C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.",

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T1 - The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C 6Li and C 12Li

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AU - Nishimura, Takatoshi

AU - White, John W.

PY - 2012/4/16

Y1 - 2012/4/16

N2 - Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C 6Li or C 12Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The 13C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.

AB - Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C 6Li or C 12Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The 13C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.

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U2 - 10.1021/ic300269n

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JO - Inorganic Chemistry

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IS - 8

ER -

The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C ₆Li and C ₁₂Li

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