The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C 6Li and C 12Li

Mark J. Henderson; Takatoshi Nishimura; John W. White

doi:10.1021/ic300269n

The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C ₆Li and C ₁₂Li

Mark J. Henderson
, Takatoshi Nishimura
, John W. White^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C ₆Li or C ₁₂Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The ¹³C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.

Original language	English
Pages (from-to)	4426-4428
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	8
DOIs	https://doi.org/10.1021/ic300269n
Publication status	Published - 16 Apr 2012

Access to Document

10.1021/ic300269n

Cite this

@article{604861e972ca4c1a825aa0487efc94d7,

title = "The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C 6Li and C 12Li",

abstract = "Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C 6Li or C 12Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 {\AA}. The 13C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.",

author = "Henderson, \{Mark J.\} and Takatoshi Nishimura and White, \{John W.\}",

year = "2012",

month = apr,

day = "16",

doi = "10.1021/ic300269n",

language = "English",

volume = "51",

pages = "4426--4428",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "8",

}

TY - JOUR

T1 - The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C 6Li and C 12Li

AU - Henderson, Mark J.

AU - Nishimura, Takatoshi

AU - White, John W.

PY - 2012/4/16

Y1 - 2012/4/16

N2 - Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C 6Li or C 12Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The 13C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.

AB - Liquid N,N,N′,N′-tetramethyl-ethane-1,2-diamine (tmeda) was intercalated into preprepared C 6Li or C 12Li. X-ray diffraction from the ternary compound indicates an identity period of 11.5 Å. The 13C NMR line shifts show that tmeda molecules form a screen between the graphene planes and the lithium ions. Small-angle X-ray scattering showed that no higher structural ordering was present but revealed a progressive roughening of the surfaces with successive intercalation of lithium and amine into the graphite galleries.

UR - https://www.scopus.com/pages/publications/84859795939

U2 - 10.1021/ic300269n

DO - 10.1021/ic300269n

M3 - Article

SN - 0020-1669

VL - 51

SP - 4426

EP - 4428

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

The intercalation of N, N, N′, N′ -tetramethyl-ethane-1,2- diamine (tmeda) into C ₆Li and C ₁₂Li

Abstract

Access to Document

Other files and links

Fingerprint

Cite this