The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis

Liam K. Burt; Anthony F. Hill

doi:10.1002/anie.202424699

The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis

Liam K. Burt, Anthony F. Hill^*

^*Corresponding author for this work

The Australian National University

Research output: Contribution to journal › Article › peer-review

Abstract

Heterobimetallic μ-methylidyne complexes [WPt(μ₂-CH)(CO)₂L₂(Tp*)], where L₂=(PPh₃)₂, (PPh₃)(CO), (dppe), (PPh₃)(CNC₆H₂Me₃), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.

Original language	English
Article number	e202424699
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	64
Issue number	9
Early online date	20 Jan 2025
DOIs	https://doi.org/10.1002/anie.202424699
Publication status	Published - 24 Feb 2025

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title = "The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis",

abstract = "Heterobimetallic μ-methylidyne complexes [WPt(μ2-CH)(CO)2L2(Tp*)], where L2=(PPh3)2, (PPh3)(CO), (dppe), (PPh3)(CNC6H2Me3), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.",

keywords = "carbido complexes, carbyne complexes, fischer tropsch synthesis, methylidyne complexes, polymetallic complexes",

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AU - Hill, Anthony F.

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N2 - Heterobimetallic μ-methylidyne complexes [WPt(μ2-CH)(CO)2L2(Tp*)], where L2=(PPh3)2, (PPh3)(CO), (dppe), (PPh3)(CNC6H2Me3), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.

AB - Heterobimetallic μ-methylidyne complexes [WPt(μ2-CH)(CO)2L2(Tp*)], where L2=(PPh3)2, (PPh3)(CO), (dppe), (PPh3)(CNC6H2Me3), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.

KW - carbido complexes

KW - carbyne complexes

KW - fischer tropsch synthesis

KW - methylidyne complexes

KW - polymetallic complexes

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ER -

The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis

Abstract

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