The origin of surface stress induced by adsorption of iodine on gold

Drew R. Evans, Vincent S.J. Craig*

*Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    10 Citations (Scopus)

    Abstract

    The cantilever technique for the measurement of film stress on both macroscopic and microscopic cantilevers is validated, then applied to the experimental determination of film stress induced by the adsorption of a monolayer of iodine onto a gold substrate. A model is proposed that relates the change in the interatom potential upon chemisorption of iodine onto gold to the measured film stress. Excellent agreement is found with the experimentally determined value. This result gives insight into the origins of film stress that is observed in all thin film and coating applications.

    Original languageEnglish
    Pages (from-to)19507-19514
    Number of pages8
    JournalJournal of Physical Chemistry B
    Volume110
    Issue number39
    DOIs
    Publication statusPublished - 5 Oct 2006

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