The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids

Christina L.L. Chai; Ruth C. Johnson; Jerome Koh

doi:10.1016/S0040-4020(01)01160-7

The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids

Christina L.L. Chai^*, Ruth C. Johnson, Jerome Koh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.

Original language	English
Pages (from-to)	975-982
Number of pages	8
Journal	Tetrahedron
Volume	58
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4020(01)01160-7
Publication status	Published - 28 Jan 2002

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AU - Koh, Jerome

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N2 - The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.

AB - The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.

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KW - Diels-Alder

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U2 - 10.1016/S0040-4020(01)01160-7

DO - 10.1016/S0040-4020(01)01160-7

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JO - Tetrahedron

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The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids

Abstract

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