The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids

Christina L.L. Chai; Ruth C. Johnson; Jerome Koh

doi:10.1016/S0040-4020(01)01160-7

The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids

Christina L.L. Chai^*, Ruth C. Johnson, Jerome Koh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.

Original language	English
Pages (from-to)	975-982
Number of pages	8
Journal	Tetrahedron
Volume	58
Issue number	5
DOIs	https://doi.org/10.1016/S0040-4020(01)01160-7
Publication status	Published - 28 Jan 2002

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title = "The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids",

abstract = "The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.",

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T2 - New routes to functionalised carbocyclic amino acids

AU - Chai, Christina L.L.

AU - Johnson, Ruth C.

AU - Koh, Jerome

PY - 2002/1/28

Y1 - 2002/1/28

N2 - The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.

AB - The reactivities and selectivities of the Diels-Alder reactions of acyclic dehydroalanine esters and cyclic dehydroalanines derived from piperazine-2,5-diones with 1,3-dienyl cobaloxime complex are reported. From our studies we demonstrate the use of the activated organocobalt diene in a 'combinatorial' approach to the synthesis of functionalised cyclic amino acids and derivatives from a single cycloaddition reaction.

KW - Amino acids and derivatives

KW - Diels-Alder

UR - https://www.scopus.com/pages/publications/0037185449

U2 - 10.1016/S0040-4020(01)01160-7

DO - 10.1016/S0040-4020(01)01160-7

M3 - Article

SN - 0040-4020

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SP - 975

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JO - Tetrahedron

JF - Tetrahedron

IS - 5

ER -

The reactivities of dehydroalanine derivatives towards 1,3-dienyl cobaloxime complex: New routes to functionalised carbocyclic amino acids

Abstract

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