The structure of Nb5O12F

Sven Lidin; Franziska Rohrer; Ann Kristin Larsson

doi:10.1016/S1293-2558(02)01333-X

The structure of Nb₅O₁₂F

Sven Lidin, Franziska Rohrer, Ann Kristin Larsson

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound was synthesized according to Andersson Acta Chem. Scand. 18 (1964) 2233. The structure is an incommensurately modulated variation of the UO₃ structure, in a (3 + 1)-dimensional super space description isostructural to the composite phases (1 - x)Ta₂O₅•xWO₃ Acta Crystallogr., Sect. B 52 (1996) 223 and Acta Crystallogr., Sect. B 51 (1995) 709. The compound crystallizes in the orthorhombic system with cell parameters 3.936(3), 6.153(2), 3.656(1) Å. The superspace group is X: Pmmm(00γ):1s1̄, where X refers to a non-standard superspace centering with the lattice vector (0 1/12 1/12 1/12), and γ = 1.61 is the modulation wave vector.

Original language	English
Pages (from-to)	767-772
Number of pages	6
Journal	Solid State Sciences
Volume	4
Issue number	6
DOIs	https://doi.org/10.1016/S1293-2558(02)01333-X
Publication status	Published - 2002
Externally published	Yes

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title = "The structure of Nb5O12F",

abstract = "The title compound was synthesized according to Andersson Acta Chem. Scand. 18 (1964) 2233. The structure is an incommensurately modulated variation of the UO3 structure, in a (3 + 1)-dimensional super space description isostructural to the composite phases (1 - x)Ta2O5•xWO3 Acta Crystallogr., Sect. B 52 (1996) 223 and Acta Crystallogr., Sect. B 51 (1995) 709. The compound crystallizes in the orthorhombic system with cell parameters 3.936(3), 6.153(2), 3.656(1) {\AA}. The superspace group is X: Pmmm(00γ):1s{\=1}, where X refers to a non-standard superspace centering with the lattice vector (0 1/12 1/12 1/12), and γ = 1.61 is the modulation wave vector.",

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AU - Lidin, Sven

AU - Rohrer, Franziska

AU - Larsson, Ann Kristin

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AB - The title compound was synthesized according to Andersson Acta Chem. Scand. 18 (1964) 2233. The structure is an incommensurately modulated variation of the UO3 structure, in a (3 + 1)-dimensional super space description isostructural to the composite phases (1 - x)Ta2O5•xWO3 Acta Crystallogr., Sect. B 52 (1996) 223 and Acta Crystallogr., Sect. B 51 (1995) 709. The compound crystallizes in the orthorhombic system with cell parameters 3.936(3), 6.153(2), 3.656(1) Å. The superspace group is X: Pmmm(00γ):1s1̄, where X refers to a non-standard superspace centering with the lattice vector (0 1/12 1/12 1/12), and γ = 1.61 is the modulation wave vector.

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The structure of Nb₅O₁₂F

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