Abstract
The complexes [M(η2-OCCR)(CO)L(Tp)] [M = Mo, W; L = P(OMe)3, PMe2Ph, PPh3; R = C6H4Me-4; Tp = hydrotris(pyrazol-1-yl)borate] are obtained from [M(≡CR)(CO)2(Tp)] and L under photolysis and these react with Lawesson's reagent (S2PC6H4OMe-4)2 to provide thioketenyl complexes [M(η2-SCCR)(CO)L(Tp)] one example of which (M = W, L = PMe2Ph) is also obtained from the reaction of [W(η2-ClCCR)Cl(CO)(Tp)] with NaSH in the presence of PMe2Ph.
Original language | English |
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Pages (from-to) | 1177-1178 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 10 |
DOIs | |
Publication status | Published - 1996 |
Externally published | Yes |