TY - JOUR
T1 - The synthesis of eta(2)-thioketenyl complexes of molybdenum and tungsten
AU - Hill, AF
AU - Malget, JM
PY - 1996/5/21
Y1 - 1996/5/21
N2 - The complexes [M(eta(2)-OCCR)(CO)L(Tp)] [M = Mo, W; L = P(OMe)(3), PMe(2)Ph, PPh(3); R = C(6)H(4)Me-4; Tp = hydrotris(pyrazol-1-yl)borate] are obtained from [M(=CR)(CO)(2)(Tp)] and L under photolysis and these react with Lawesson's reagent (S(2)PC(6)H(4)OMe-4)(2) to provide thioketenyl complexes [M(eta(2)-SCCR)(CO)L(Tp)] one example of which (M = W, L = PMe(2)Ph) is also obtained from the reaction of [W(eta(2)-CICCR)Cl(CO)(Tp)] with NaSH in the presence of PMe(2)Ph.
AB - The complexes [M(eta(2)-OCCR)(CO)L(Tp)] [M = Mo, W; L = P(OMe)(3), PMe(2)Ph, PPh(3); R = C(6)H(4)Me-4; Tp = hydrotris(pyrazol-1-yl)borate] are obtained from [M(=CR)(CO)(2)(Tp)] and L under photolysis and these react with Lawesson's reagent (S(2)PC(6)H(4)OMe-4)(2) to provide thioketenyl complexes [M(eta(2)-SCCR)(CO)L(Tp)] one example of which (M = W, L = PMe(2)Ph) is also obtained from the reaction of [W(eta(2)-CICCR)Cl(CO)(Tp)] with NaSH in the presence of PMe(2)Ph.
KW - Bis(cyclopentadienyl)titanium
KW - Reagent
UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=anu_research_portal_plus2&SrcAuth=WosAPI&KeyUT=WOS:A1996UN96900044&DestLinkType=FullRecord&DestApp=WOS_CPL
U2 - 10.1039/cc9960001177
DO - 10.1039/cc9960001177
M3 - Article
SN - 1359-7345
SP - 1177
EP - 1178
JO - Chemical Communications
JF - Chemical Communications
IS - 10
ER -